沼气提纯―常规与功能吸收剂提纯沼气的研究.docVIP

摘　要 本文通过采用改良热钾碱法和功能化离子液体吸收法进行沼气的脱碳工艺条件的优化研究，分别探索了CO2的静态吸收量随吸收剂各组分的浓度、操作温度、操作压强和吸收时间的变化情况。通过数据分析得到，对于单组分CO2吸收过程,改良热钾碱法中吸收剂各组分浓度的最佳配比为K2CO3(30%)，NaVO3·2H2O(0.85%)，NaBO2·4H2O(2%)；最适温度为325.15 K；最适压强为130 KPa左右。功能化离子液体吸收法中复配吸收剂([NH2-C3mim]Br与水)的最佳浓度为50%，最适温度为299.15 K，最适压强165 KPa左右改良热钾碱法在最佳实验条件下每摩尔吸收剂吸收CO2的量为0.756 mol；功能化离子液体吸收法在最佳实验条件下每摩尔吸收剂吸收CO2的量为0.336 mol。相对而言，改良热钾碱法吸收效果更好一些，但离子液体法达到吸收饱和的时间比热钾碱法要短很多。 关键词: 沼气 脱碳 改良热钾碱法 功能化离子液体 Biogas Purification―study about Conventional and Functional Absorbent Purification of Biogas Sun Jun Directed by Liu Wei-jie and Li Tian-cheng Abstract This?article?studies the optimization conditions of CO2 removal from biogas based on Hot Potassium Carbonate method and functional?ionic liquid?absorption method, and?to explore?the CO2?absorption and?the time taken to achieve saturation states ?based on variation of parameters such as?the component of?the absorbent ,the temperature, and pressure. Based on the data analysis, with the improved hot potassium alkali method, we obtain the optimal ration of combination of components that constitute the absorbent concentration [K2CO3(30%)，NaVO3·2H2O(0.85%)，NaBO2·4H2O(2%)]as?well?as?the most appropriate temperature(325.15 K) ,?the initial pressure(130 KPa) , the absorptive amount of CO2 (0.756 mol/mol).While with the?functionalized ionic liquid?absorption method, we obtain the optimal concentration of [NH2-C3mim] Br(50%), the most appropriate temperature (299.15 K),the initial pressure(165 KPa),and the absorptive amount of CO2(0.336 mol/mol).While the improved hot potassium alkali method has the better absorbing efffect and the?functionalized ionic liquid?absorption method costs shorter time. Keywords Biogas Decarbonization Improved hot potassium?alkali Functional ionic liquid沼气提纯―常规与功能化吸收剂提纯沼气的研究 1　前言 1.1 课题提出的研究意义 能源是人类社会存在与发展的物质基础。过去200多年，建立在煤炭、石油、天然气等化石燃料基础上的新能源体系极大的推动了人类社会的发展。然而，人们在物质生活和精神生活不断提高的同时，也越来越感悟到大规模使用化石燃料所带来的严重后果；资源日益枯竭，环境不断恶化，还诱发不少国与国之间、地区之间的政治经济纠纷，甚至