Thermodynamics of Dielectric Relaxations in Complex Systes在复杂的系统中的介电弛豫热力学.pptVIP

下载本文档

1
0
约1.04万字
约 41页
2018-06-19 发布于福建
举报
版权申诉

Thermodynamics of Dielectric Relaxations in Complex Systes在复杂的系统中的介电弛豫热力学.ppt

1、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。。
2、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
3、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
4、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
5、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
6、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
7、VIP文档为合作方或网友上传，每下载1次，网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档

Thermodynamics of Dielectric Relaxations in Complex Systes在复杂的系统中的介电弛豫热力学

Thermodynamics of Dielectric Relaxations in Complex Systems Static dipoles It is necessary to found the Relation between microscopic polarizability and macroscopic permittivity. From the phenomenological point of view, it is necessary to know the kinetic of the Polarization. From molecular one it’s required the knowledge of the effective Electric field at which the dipole is subjected. 4 different ways are proposed to evaluate the molecular: Claussius – Mossotti Debye Onsager Fouss – Kirkwood Lorentz local field Lorentz local field Onsager, generalize the Debye equation taking into account the effect of the if the permanent dipole moment of a molecule by the polarization of the environment. 1 – The cavity field, G, (the field produced in the empty cavity by the external field.) 2 - The reaction field, R (the field produced in the cavity by the polarization induced by the surrounding dipoles). Onsager treatment of the cavity differs from Lorentz’s because the cavity is assumed to be filled with a dielectric material having a macroscopic dielectric permittivity. Also Onsager studies the dipolar reorientation polarizability on statistical grounds as Debye does. The remaining problem is to take into account the interaction between dipoles Kirkwood and Fr?hlich develop a fully statistical argument to determine the short – range dipole – dipole interaction. Debye equation First order kinetic: Decay function: In frequency domain Debye equation doesn’t represent in a good way the experimental data. Some modifications in the decay function was proposed by Williams – Watt, ussing a previously Kolraush equation. Advantages: represent better the experimental data. Disadvantages: the ? parameter it’s an artificial parameter and no molecular relation for this parameter have been yet found DISPERSION RELATIONS The real and imaginary part of the complex permittivity are, respectively, the cosine and sine Fourier transforms of the same function, that is, ?(?). As