代_孕__堵塞原_因.pptVIP

tsnl Synthesis and Application of Nanosize Semiconductors for Photoxidation of Toxic Organic Chemicals Acknowledgement: Div. Of Materials Science and Engineering, Office of Science, US Dept. of Energy under contract DE-AC-04-AL8500. Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed-Martin Company, for the US Dept. of Energy. This work performed under the aupices of the DOE Environmental Science/Environmental Research (ER/ES) Program. Industrial Solvents in the Environment (Impregnated Sediments, Water Table) Brief History of the problem and possible remediation approaches (Bioremediation, Soil Washing, Adsorption, Photooxidation) Photocatalysis using UV light and nanosize TiO2 and SnO2. Photocatalysis using visible light and MoS2 nanoclusters. J.P. Wilcoxon, Nanostructures and Advanced Materials Chemistry Sandia National Laboratories Albuquerque, N.M., 87185-1421 jpwilco@sandia.gov Colloborators: T.R. Thurston, P. Provencio, G.A. Samara Talk Outline Typical Scenario-Dense Non-Aqueous Solvent Pools Examples- Cleaning Solvents- Tri-Chloroethylene (TCE) Herbicides/Fungacides/Pesticides (Pentachlorophenol (PCP), DDT) Explosives (e.g. TNT) Major Remediation Issues- 1) Low Solubility (1-10 ppm) in water provides continuous leaching with time 2) Treatment of large volumes of highly diluted toxins 3) Cost of treatment Rain Organic Pool in Soil Water Table Slow Leaching Possible Treatment Approaches- Conventional Treatment Options: 1)Filtration and/or Adsorption of toxic chemicals in aqueous supernatant from Step 1 2)Chemical Oxidation or Total Mineralization of the the Organics 3)Deep UV Photooxidation of the Organics 4)Photocatalytic oxidation of the Organics (e.g. colloidal titania slurries) Step 1: Excavation, Soil Washing Cost and large volumes involved are the principal practical concerns. Alternative Approach Use stable, inorganic, semiconductor nanoclusters with tunable bandgaps to oxidize organic chemicals using sun