各单因素对改性稻壳吸附锌的影响.doc

涂铁污泥吸附处理中低浓度氨氮废水 柴立元1,2 罗仙平1 丁丽超陈云嫩江西理工大学资源与环境工程学院，江西赣州341000） 摘 要：表明：，拟二级速率方程 关键词：氨氮废水，氯化铁改性，污泥，吸附 中图分类号： 文献标志码：A The treatment of wastewater containing medium-low ammonium-nitrogen using sewage sludge modified by ferric chloride Chai liyuan1,2, Luo xianping1, Ding lichao1, Chen yunnen1* (1. School of Resource and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou,341000, China; 2. School of Metallurgical Science & Engineering, Central South University, Changsha, 410083, China.) Abstract：ontamination containing nitrogen untreated or treated incompletely can be harmful to environment. The traditional ways are inefficient for treating medium-low ammonium-nitrogen. Using residual activated sludge from sewage plant modified 2 h by ferric chloride as adsorbent, wastewater containing medium-low ammonium-nitrogen was treated. The experimental results indicated that the removal of ammonium- nitrogen can attained above 95% when ferric chloride 0.15 mol/L, dosage 5 g/L, pH 9, contact 40 min at room temperature. And the adsorption process accords with pseudo second-order kinetics equation. Under the experimental condition, initial ammonium-nitrogen concentration and COD being 102.68 mg/L and 362 mg/L in actual industrial wastewater was reduced to 9.2 mg/L and 83 mg/L for NH4+ and COD respectively after adsorption treatment, which achieved <Integrated wastewater discharge standard>（NH4+<15 mg/Land COD<100 mg/L）. Keywords：wastewater containing ammonium-nitrogen, modified by ferric chloride, sewage sludge, adsorption 1 前言 氨氮废水来源很广且排放量大，如化肥、焦化、石化、制药、垃圾填埋场等均产生大量氨氮废水。氨氮废水对环境的影响已引起环保领域和全球范围的重视，近20年来，国内外对氨氮废水处理方面开展了较多的研究，主要涉及生物法、物化法的各种处理工艺，如生物法有硝化[1,2]和藻类养殖；物化法有土壤灌溉、吸附法[3~6]、氨吹脱[7]、离子交换法[8]、蒸馏[9]、化学沉淀法[10,11]、反渗透[12,13]、折点氯化、电化学处理、催化裂解等，但是这些方法对于中低浓度氨氮废水的处理效率都不高。 污水处理厂的污泥中大约含有70 %的粗蛋白质，25 %左右的碳水化合物，而无机灰分仅占5 %左右。污泥在一定高温下可热解得到多孔衍生材料，不仅成本低廉，而且具有较好的吸附性能，可应用于污水处理[14]、有害气体吸附等，同是采用氯化锌、硫酸、磷酸等作为活化剂在高温条件下对污泥进行活化，并将其用于处理重金属废水处理[15,16]。