影响Cu-doping碳化钼催化剂的结构和性能对低温的草酸二甲酯加氢乙醇：（Effect of Cu-doping on the structure and performance of molybdenum carbide catalyst for low-temperature hydrogenation of dimethyl oxalate to ethanol）.pdfVIP

Applied Catalysis A: General 529 (2017) 143–155 Contents lists available at ScienceDirect Applied Catalysis A: General j o u r n a l h o m e p a g e: w w w. elsev /locate/apc ata Effect of Cu-doping on the structure and performance of molybdenum carbide catalyst for low-temperature hydrogenation of dimethyl oxalate to ethanol Yanting Liu a,b , Jian Ding c , Jicheng Bi a , Yanping Sun d , Juan Zhang a , Kefeng Liu e , Fanhua Kong e , Haicheng Xiao e , Jiangang Chen a,∗ a State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, 030001, China b University of Chinese Academy of Sciences, Beijing, 100039, China c School of Chemical Engineering, Inner Mongolia University of Science Technology, Baotou, 014010, China d Taiyuan University of Technology, Taiyuan, 030001, China e PetroChina Petrochemical Research Institute, Beijing, 100195, China a r t i c l e i n f o a b s t r a c t Article history: Several copper-doped molybdenum carbide (Cu–Mo C) nanomaterials for the hydrogenation of dimethyl 2 Received 28 July 2016 oxalate (DMO) to ethanol at low temperature (e.g., 473 K) have been developed through a facile solid- Received in revised form 6 November 2016 state pyrolysis method. Characterization techniques including X-ray diffraction, scanning/transmission Accepted 9 November 2016 electron microscopy, N -physisorption, energy-dispersive spectroscopy, and X-ray phot