雾化al合金粉的燃烧性能及机理分析-combustion performance and mechanism analysis of atomized al alloy powder.docxVIP

华 华 中 科 技 大 学 硕 士 学 位 论 文 万方数据 万方数据 Abstract In this paper, a series of Al alloy powders with different mass content of Mg has been prepared by rapid solidification technology of inert gas atomization. The regular proportions of phase composition in alloys were obtained by different heat treatment processes. The DTA/TG results showed that the complete combustion temperature decreased with the increase of Mg content. And the different exothermic peaks were caused by oxidation of different phase component. The combustion performance of alloy powders with furnace cooled was better than with air cooled under lower temperature (430°C~650°C). The combustion process and mechanism showed that the main combustion process of alloy powders could be divided into two steps roughly. Under the range of 430°C~650°C, Mg-rich phases were selective oxidized and the nano-flake Al with large specific surface was formed, which was corresponding to low-temperature exothermic peak on the DTA curves. The oxide products were mainly composed of MgO and MgAl2O4. Under the range of 700°C~1200°C, the remainder of the Al-rich phase was oxidized, which is corresponding to high-temperature exothermic peak on the DTA curves. The final oxide products were composed of MgAl2O4, MgO and Al2O3. In the whole process of combustion, the flake Al with large specific surface and the brittle MgO layer formed by combustion of Mg-rich phases were responsible for the excellent combustion performance of micron atomized Al-Mg powders. Furthermore, the Zn-Mg-Al ternary alloy powders were studied. The exothermic peaks temperature decreased with the increase of the Zn content from 2wt% to 10wt%. At last, the samples with the same content of Al in binary and ternary alloy powders were studied. The results showed that the ternary alloy powders perform better performance because the Zn addition promotes the formation of β-Al3Mg2 in Zn-Mg-Al alloy powders. Key words: Al-Mg alloy powders; Atomization method; Combus