两种魔芋葡甘聚糖羧酸酯的制备及其性能的研究论文.docVIP

Ⅲ 两种魔芋葡甘聚糖羧酸酯的制备及其性能的研究 The preparation of two kinds of KGM carboxylate and research their properties 摘 要 制备了两种魔芋葡甘聚糖羧酸酯并研究其相关性能。以魔芋葡甘聚糖（KGM）为原料，氢氧化钠为催化剂，乙酸酐为改性剂，制备了魔芋葡甘聚糖乙酸酯；以吡啶为催化剂，正丁酰氯为改性剂，在苯的反应体系中制备了魔芋葡甘聚糖丁酸酯。分别研究了不同反应条件对以上两种魔芋葡甘聚糖脂肪酯的取代度（DS）和吸水性的影响。运用傅立叶红外光谱仪(FTIR)对KGM乙酸酯和KGM丁酸酯进行了表征，利用布袋法检测了它们的吸水性。结果表明，KGM乙酸酯和KGM丁酸酯的羰基(C=O)特征吸收峰较KGM明显增强，吸水性随着DS的增加而降低，在DS相同的情况下，KGM乙酸酯比KGM丁酸酯吸水性强。 关键词：魔芋葡甘聚糖；酯化反应；吸水性 ABSTRACT Fabricate two kinds of KGM carboxylate and research their properties. Manufacture KGM acetate with KGM as raw materials, sodium hydroxide as catalyst, and acetic anhydride as modifier; fabricate KGM butyric acid ester in the reaction system of benzene. Study seperately the influence of the two kind of KGM carboxylate of the HYPERLINK app:ds:degree \t degree HYPERLINK app:ds:of \t of HYPERLINK app:ds:substitution \t substitution and HYPERLINK app:ds:water%20absorbability \t _self water absorbability under the reaction condition.Use FTIR spectrometer?to characterize the KGM and KGM carboxylate, and detect the HYPERLINK app:ds:water%20absorbability \t _self water absorbability of them in bag process. The results show that the HYPERLINK app:ds:absorption%20peak \t _self absorption peak of HYPERLINK app:ds:carbonyl%20(group) \t _self carbonyl group features of the KGM acetate and HYPERLINK app:ds:%20%20butyrate \t _self butyrate increases, and the HYPERLINK app:ds:water%20absorbability \t _self water absorbability lowers as the increasing of the DS.In the same DS circumstances,KGM acetate ’s absorbent higher then KGM butyrate’s. Key words：KGM; esterification; absorbent PAGE \* MERGEFORMAT 3 目 录 HYPERLINK \l _Toc28217 郑重声明 Ⅰ HYPERLINK \l _Toc28217 摘要 Ⅱ HYPERLINK \l _Toc28217 ABSTRACT Ⅲ HYPERLINK \l _Toc28217 目录 1 TOC \o 1-3 \h \u HYPERLINK \l _Toc28217 第一章 综 述 PAGEREF _Toc28217 3 HYPERLINK \l _Toc29779 1.1 引言 PAGEREF _Toc29779 3 HYPERLINK \l _Toc12519 1.2 魔芋葡甘聚糖的性质 PAGEREF _Toc12519 4 HYPERLINK \l _Toc2421 1.3 魔芋葡甘聚糖的结构 PAGER