稀土改性bi2o3-tio2复合光催化剂的制备及其催化性能-preparation and catalytic performance of rare earth modified bi2o3 - tio _ 2 composite photocatalyst.docxVIP

分别含有5.05%,4.26%和3.57%的碳，且对可见光均有明显的吸收，当用量为2.5g/L时，25mg/L的甲基橙溶液在500W氙灯下辐射60min后，脱色率分别达到了94.3%,96.2%和97.5%，其表观反应速率分别是P25的2.1,2.4和2.7倍；循环实验则表明复合材料光催化性能较稳定。关键词：光催化TiO2Bi2O3稀土复合半导体AbstractPhotocatalysisissougthafterbyenvironmentalistsbecauseofitsefficiency,energyconvervationandno-secondarypollution.TiO2isregardedasanidealphotocatalystduetoitsstrongoxidation,highstability,non-toxicityandcheapness.Unfortunately,itscommercializa-tionisgreatlyrestrictedbythetwobottleneckfactorswhichincludethelowlightefficiencyandquantumyield.WeprepareBi2O3-TiO2andrareearthsmodifiedBi2O3-TiO2compositesforobtainingmoreavtivephotocatalyst.Theirstructuresandpropertieshadbeeninvestigatedaswellastheirphotocatalyticactivities.Thisdissertationconsistsoffollowingcontents.Bi2O3-TiO2compositeswerepreparedbysol-gelmethod,andtheirstructuresandpropertieswereextensivelycharacterizedbyTEM,HRTEM,XRD,Raman,FT-IRandUV-visDRS.ThecharacterizationresultsrevealedthatBi2O3andTiO2coexistedintheresultingsamples.CompoundwithlowamountBi2O3couldnotonlyinhibitthephasetransformationfromanatasetorutileandthecrystalgrowth,butalsowidenTiO2responserangetowardslight.Thehighestphotocatalyticactivitywasgottenwhentheratioofn(Bi):n(Ti)was0.0175.Nd3+modifiedofBi2O3-TiO2coupledcompositeswerepreparedbysol-gelmethod,theirstructuresandpropertieswereextensivelycharacterizedbythermalanalysis,TEM,HRTEM,XRD,Raman,FT-IRandUV-visDRS.ThecharacterizationresultsrevealedthatNd2O3attachedtothesurfaceofBi2O3-TiO2.CompoundwithlowamountNd2O3couldincreasethedispersionofBi2O3-TiO2.Thehighestphotocatalyticactivitywasgottenwhentheratioofn(Nd):n(Bi)was25%.La3+modifiedofBi2O3-TiO2coupledcompositeswerepreparedbycolloidalblendingmethod,andtheirstructuresandpropertieswereextensivelycharacterizedbyTEM,HRTEM,XRD,Raman,FT-IRandUV-visDRS.Thecharacterizationresultsthatrevealedamorphous-anatasewasobtainedat300or350oC,buttheanatasewasobtainedat400or450oC.TheabsorptionofLa/Bi2O3-TiO2inthevisiblelightregionwouldgraduallyweakenastemperaturerose.Thehighestphotocatalytic