铁山垅钨矿细泥综合利用工艺分析-process analysis of comprehensive utilization of fine slime in tieshanlong tungsten mine.docxVIP

I I 摘 要 从钨矿细泥中有效综合回收各种有用矿物是钨选矿的难点。本文针对铁山垅钨细泥成 分复杂，选别流程繁琐，采用有毒性的胂酸类捕收剂进行选别作业的现状。采用脱硫-离 心选矿-浮选流程取代现有流程，并采用螯合捕收剂 GYB 取代胂酸类捕收剂完成实际矿物 试验，取得较好试验指标。并在此基础上，通过红外光谱测试和离心机受力分析对黑钨矿 选别机理进行了探讨。 鉴于对细泥性质的深入了解以及对选厂流程考察的基础上，对实际矿物进行工艺研 究。试验结果表明：在对原矿进行重选与磁选流程探讨时，发现重选流程优于磁选流程。 考虑硫化矿的综合回收，对离心选矿-脱硫与脱硫-离心选矿流程进行考察，确定采用脱硫 -离心选矿，在实现资源综合利用的基础上，减少硫化矿对钨矿物选别的影响。采用新型 离心机得到离心尾矿 WO3 品位为 0.058%，低于选厂尾矿品位 WO30.09%，达到排放标准， 减少摇床扫选流程。离心重选后的精矿品位达到 WO39.65%，采用磁选与浮选流程对离心 精矿进行精选富集，结果表明浮选指标优于磁选指标。采用浮选流程精选，运用 GYB 替 代选厂苄基胂酸作为黑钨浮选捕收剂，加入 Pb(NO3)2 作为活化剂，运用一次粗选、二次 精选、一次扫选，得到 WO3 60.38%，总回收率为 65.70%的钨精矿，比原厂流程对钨的回 收增加 2.65 个百分点。成功应用 GYB 捕收剂取代原选厂胂酸类捕收剂，解决无毒、环保 问题。从而实现节能、环保、增产、增量。 红外光谱测试结果表明：GYB 在黑钨表面能形成化学吸附，加入硝酸铅后吸附更加 明显。对矿粒在离心选矿机中的受力进行分析结果表明：试验所用转鼓转速与理论值相符。 关键词：钨细泥；选矿工艺；浮选；离心选矿机；湿式磁选机 I II Abstract Recovering various useful minerals effective and comprehensive from tungsten ore fine mud is a hard problem of tungsten ore recovering . Based on the situation of that,the composition of Tie Shan Long’s tungsten fine mud is complex , sorting process cumbersome and using toxic arsine acids collector in the sorting operation.Using desulfurization - centrifugal concentrator - flotation process to replace the existing processes and chelating collector of GYB replace the arsine acids collector to complete the actual mineral test to obtain a better test indicators. And on this basis, through the test of infrared spectroscopy and centrifuge stress analysis discuss the wolframite sorting mechanism. On the basis of deeply understanding of the nature and the observation of Tie Shan Long tungsten mine produce process，a study on process of actual minerals. Experimental results show that: using gravity and magnetic separate the ore, found the gravity separation process is better than magnetic separation process. Consider the comprehensive recovery of sulfide ore, compare centrifugal concentrator-desulfurization with desulfurization-centrifugal concentrator process and determine the desulfurization - centrifugal is better .To achie