氰化尾渣中铁浸出对金银浸出率影响.doc

PAGE Doi：10.3969/j.issn.1007-7545.2015.12 Doi：10.3969/j.issn.1007-7545.2015.12.013 张跃红1，李云2，魏晋3，王云2，栾东武3，刘洪晓4 (1.青海省第一地质矿产勘察院，青海平安 810600；2.北京矿冶研究总院，北京 100160； 3.招远市招金金合科技有限公司，山东招远 265400；4.新疆星塔矿业有限公司，新疆托里 834500) 摘要：对难处理金精矿两段焙烧提金流程中的氰化尾渣进行强化酸浸，酸浸过程中氧化铁矿物的溶解而使其中包裹的金得到解离并裸露，在氰化浸出过程中容易被浸出。研究表明，随着焙砂中氧化铁相包裹体的逐步酸溶，其酸浸渣中的金、银的氰化浸出率也随之显著提高。该预处理方法为提高难处理金精矿中金、银的浸出回收率提供了一种有效的途径。 关键词：难处理金精矿；氰化尾渣；氧化铁包裹；金；银；酸浸 中图分类号：TF831 文献标志码：A 文章编号：1007-7545（2015）12-0000-00 Effect of Dissolving of HYPERLINK /ferric%20oxide Ferric Oxide from Calcine Cyanide Residue on Leaching of Gold and Silver ZHANG Yue-hong1, LI Yun2, WEI Jin3, WANG Yun2, LUAN Dong-wu3, LIU Hong-xiao4 (1. Qinghai First HYPERLINK /surveying%20institute Surveying Institute of Geology and Minerals, Ping’an 810600, Qinghai, China; 2. Beijing General Research Institute of Mining Metallurgy, Beijing 100160, China; 3. Zhaoyuan City Zhaojin Jinhe Science and Technology Ltd, Zhaoyuan 265400, Shandong, China; 4. Xinjiang Xingta Kuangye Co. Ltd, Tuoli 834500, Xinjiang, China;) Abstract：Calcine cyaniding-residue produced from two-stage roasting of refractory gold concentrate was leached with sulfuric acid. Gold can be easily cyaniding leached after ferric oxide was dissociated and unlocked from the wrapped gold during acid leaching. Extraction efficiency of gold and silver raised HYPERLINK /step%20by%20step remarkably when ferric oxide was dissociated continuously, which is proved to be an effective pretreatment for refractory gold HYPERLINK /ore%20concentrate concentrate to improve gold and silver extraction efficiency. Key words：refractory gold HYPERLINK /ore%20concentrate concentrate; calcine cyanide residue; HYPERLINK /ferric%20oxide ferric oxide-encapsulated; gold; silver; acid leaching 目前运行的两段焙烧金精矿黄金冶炼工艺中存在的主要问题是氰化尾渣含金仍然偏高[1-4]。对焙砂与氰化尾渣进行的矿物学研究表明，渣中含金主要是氧化铁的严密包裹而不能与浸出介质充分接触所致。本文以工艺矿物学为指导，通过对金精矿两段焙烧的氰化尾渣中金的物相形态以及金在氧化铁中的包裹分析测定以及对氰化尾渣中包裹金的氧化铁进行浸出[5-6]，研究表明，随着氰化尾渣中铁的不断浸出，金的氰化浸出率随之提高，为焙砂酸浸提供了理论指导与实际应用。 1 金精矿及其焙砂提金氰化尾渣成分分析 新疆