中空tio2和tio2-zro2微球的制备及其光催化性能研究-preparation and photocatalytic properties of hollow tio _ 2 and tio _ 2 - z ro2 microspheres.docxVIP

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中空tio2和tio2-zro2微球的制备及其光催化性能研究-preparation and photocatalytic properties of hollow tio _ 2 and tio _ 2 - z ro2 microspheres.docx

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中空tio2和tio2-zro2微球的制备及其光催化性能研究-preparation and photocatalytic properties of hollow tio _ 2 and tio _ 2 - z ro2 microspheres

西安理西安理工大学硕士学位论文（3）采用硅烷偶联剂 KH832 对中空 TiO2-ZrO2 交错复合微球进行表面疏水改性，通过对改性前后的催化微球的红外光谱分析以及物理表征，证实改性后的催化微球表面接上了疏水基团。改性后的双亲性中空 TiO2-ZrO2 催化微球具有一定的界面特性，在紫外光下 60min 内对氯霉素的降解率达 80.1%，对诺氟沙星降解率达 100%，在环境废水处理技术中具有广泛应用前景。关键词：中空 TiO2; 中空 TiO2-ZrO2；光催化；交错复合微球；双亲性；降解 II Abst Abstract Title: STUDY ON PREPARATION OF HOLLOW TiO2 AND TiO2-ZrO2 AND ITS PHOTOCATALYTIC ACTIVITY Major: Chemical Engineering and Technology Name: Lv Ying Signature: Supervisor: Prof. Yao Binghua Signature: Abstract Semiconductor titanium oxide photocatalyst has become one of the mostly used photocatalysts due to its nontoxic, easy preparation and low cost and so on. However, the disadvantages such as high recombination rate of photogenerated carriers and low quantum efficiency existed in pure titanium oxide photocatalysts, and this largely limited its practical applications. Researchers have found that coupling TiO2 with other metal oxides can highly enhance the photocatalytic activity. This is attributed to the formation of heterojunction between TiO2 and other semiconductors creating new photochemical and photophysical performances which do not exist in the single semiconductor and thus achieving better charge separation in a light energy conversion system. One the other hand, due to the surface hydroxyl groups, powder photocatalysts with micro-nano size always have hydrophilic property which can easily deposit on the bottom of the reaction solution leading to second pollution. This also limited the industrial applications of TiO2. In order to solve the above mentioned problems, in this thesis, we successfully prepared TiO2-ZrO2 composite photocatalyst with hollow hybrid structure, which was further characterized using SEM, XRD, UV-vis and BET analysis. Methyl blue solution was chosen as degradation target to evaluate the photocatalytic activity of hollow TiO2-ZrO2 composite photocatalysts. Meanwhile, in order to solve the second p