阻燃抗熔滴pet的制备与结构性能测试-preparation and structural properties test of flame retardant and dropping resistant pet.docxVIP

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阻燃抗熔滴pet的制备与结构性能测试-preparation and structural properties test of flame retardant and dropping resistant pet.docx

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阻燃抗熔滴pet的制备与结构性能测试-preparation and structural properties test of flame retardant and dropping resistant pet

万方数据万方数据 greatly. The flame-retardant and anti dripping properties of PET have been improved effectively. The initial thermal stability of the samples which add additional pentaerythritol or antioxidant 1010 have been improved, and the amount of residual carbon maximum increased from 9.88% to 13.55%, the LOI value increased from 29% to 30%, the vertical combustion can reach V-0 level, the anti dripping effect have been further improved. In the CONE test, the time to arrival the peak heat release rate(tpk-HRR) and the time to arrival the peak mass loss rate(tpk-MLR) both have been delayed. the early stage of the combustion flame retardant performance have been improved. Study on carbon layer morphologies of the samples showed that: the PET which modified by the intumescent flame retardant system and add additional pentaerythritol or antioxidant 1010, all can be formed the expansion of carbon layer during thermal degradation which is dense and porous, and with the three dimensional structures. This carbon layer protect the substrate and inhibition of combustible gas overflow. Keywords: Intumescent flame retardant; Flame retardant PET; Phosphorus-based flame retardant; Anti-dripping property III 目录 HYPERLINK \l _bookmark0 引言 ............................................................................................................................................... 1 HYPERLINK \l _bookmark1 第 1 章文献综述 ........................................................................................................................... 2 HYPERLINK \l _bookmark2 1.1 聚酯燃烧熔融滴落概述 .......................................................................................................... 2 HYPERLINK \l _bookmark3 1.1.1 聚酯的燃烧机理 ................................................................................................................... 2 HYPERLINK \l _bookmark4 1.1.2 聚酯的熔融滴落 ....................................................................................................