阻燃定型剂及阻燃环氧复合材料的rtm制备-rtm preparation of flame retardant setting agent and flame retardant epoxy composites.docxVIP
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阻燃定型剂及阻燃环氧复合材料的rtm制备-rtm preparation of flame retardant setting agent and flame retardant epoxy composites
I
东华大学硕士论文 摘要
阻燃定型剂及阻燃环氧复合材料的 RTM 制备
摘 要
环氧复合材料具有比强度高、比模量高的力学性能、性能可设计 性及制造成型的多选择性等优越性能,在航空航天、汽车交通、新能 源等军事及民品领域应用越来越广泛。但因其易燃,严重影响其应用 领域的发展和扩大。
本研究结合环氧复合材料的发展需求,旨在设计和制备出低成本、 高性能的环氧复合材料,使其具有较好的阻燃性能和力学性能。因此, 开发了制备阻燃环氧复合材料的新工艺,制备 ET3228/MRP 阻燃定型 剂,并对其配方进行优化,利用 ET3228/MRP 阻燃定型剂定型玻纤增 强织物,RTM 液态成型工艺制备阻燃环氧复合材料,有效改善环氧 复合材料的阻燃性能。
采用极限氧指数(LOI)、水平垂直燃烧、差示扫描量热分析(DSC)、 热重分析(TGA)、动态机械性能测试(DMA)、锥形量热测试(CONE)、 扫描电镜(SEM)和力学性能测试等方法对 EW-220/3228 阻燃环氧 复合材料的阻燃性能、热稳定性及力学性能进行了表征和测试,并讨 论了阻燃定型剂的定型效果和阻燃机理。
结果表明:阻燃定型剂在复合材料内主要通过凝聚相阻燃。当
3228/ET3228/MRP 配比为 84.5:8:7.5 时,EW-220/3228 阻燃环氧复合
II
东华大学硕士论文 摘要
材料的 LOI 可达到 46.4%,较未添加阻燃定型剂的 EW-220/3228 复合
材料(LOI 值 29.2%),提高了 17.2%;水平燃烧测试均达到 FV-1 级, UL-94 测试均达到 V-1 级,无熔滴现象,烟浓度更小;残炭率则由 59.18% 提高到 65.27%,微胶囊化红磷在环氧复合材料中阻燃效果明显,与 在树脂基体中添加阻燃剂的传统添加方法相比,在环氧复合材料增强 织物表面涂覆阻燃定型剂粉末,既保证了复合材料液态成型工艺性, 又极大地改善了纤维增强环氧复合材料的阻燃性能,并且对纤维增强 复合材料的力学性能影响不大,可以有效提高环氧树脂复合材料的可 设计性,应用前景广阔。
关键词:RTM;环氧复合材料;微胶囊化红磷;阻燃机理;力学性能
III
ABSTRACT Donghua University
PREPARATION OF RETARDANT TACKIFIERS AND FLAME RETARDANT EPOXY COMPOSITES BY RTM
ABSTRACT
Epoxy composites have many superior performance, such as high specific strength, high specific modulus mechanical properties, performance designability and multi-selectivity of manufacturing molding, therefore, they are more and more widely used in the aerospace, automobile transportation, new energy and other military and civilian fields,. However, the flammability seriously limits its application in practice.
In this paper, in order to meet the need for expansion of epoxy composites, the low-cost and high-performance epoxy composite materials, which have superior fire-retardant properties and mechanical properties are prepared and investigated. Therefore, an innovative method for preparing flame-retardant epoxy composites is developed. MRP were
added to tackifier to prepare ET3228/MRP and optimize its formulations. Fiberglass fabric is shaped and flame retardant epoxy composites are
prepared by RTM.
Flame retardance, thermal stability and mechanica
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