蝶翅结构tio2膜在染料敏化太阳能电池中的探索研究-材料学专业论文.docxVIP

第  PAGE 14 页 受蝶翅颜色与结构之间的紧密联系所启发，本研究选择两种蝶 翅结构作为生物模板，将蝶翅结构复制在透明导电玻璃表面，并组 装成染料敏化太阳能电池（DSSC，dye-sensitized solar cell），比较其 光电性能，希望能对 DSSC 电极的研究提供新的结构，从而能获得 具有较高光捕获效率乃至高光电转化效率的 DSSC。 (1)光阳极制备及电池组装：本文采用遗态法，以钛酸四丁酯的 无水乙醇溶液为前驱体，在导电玻璃上复制了蝶翅结构。在染料 N3 乙醇溶液中浸泡 24 小时后，得到蝶翅结构 TiO2 光阳极，组装成染料 敏化太阳能电池后，添加电解液，完成电池的组装。 (2)光阳极材料表征及电池性质研究：比较研究了两种蝶翅结构 光阳极染料敏化太阳能电池的电流电压曲线，结果表明，采用蜂窝 状结构复制的光阳极组装的染料敏化太阳能电池，可获得较好的光 电性能。通过对光阳极的显微结构、成分??以及反射光谱的表征， 对电池性能的差异作出了解释。 关键词：蝴蝶，模板，二氧化钛，染料敏化太阳能电池  DYE-SENSITIZED TiO2 SOLAR CELL WITH PHOTOANODE STRUCTURE TEMPLATED FROM BUTTERFLY WING SCALES ABSTRACT Dye-sensitized nanocrystalline TiO2 solar cell (NPC, nanocrystalline photovoltaic cell) is a new type of photoelectrochemical solar cell. Because of its simple fabrication procedure，low cost，better stability and clean energy, NPC solar cell has aroused world researches and application prospect. The scientists have found out that the microstructure of photoanode is a key factor on the performance of DSSC. Therefore, developing different kinds of microstructure of photoanode is an important way to improve DSSC. Butterflies have evolved a variety of colorful wings. Studies have shown that the color is related to its micro-structure of the wings scales. For example, some butterfly wings, show black or dark grayish brown, which enables it to absorb more energy, and thus makes their own body temperature quickly rises to a suitable temperature, to increase its cold climate and high altitude the survival chances of the region. The recent research has discovered that the scales in the black area of the surface of some kind of papilionoidea wings have quasi-honeycomb like microstructure. This microstructure has been proved to absorb light as much as possible, like a trap of light. It’s said that the light will reflect times by times after entering the honeycomb. In the need of Courtship and predation, some butterflies evolved a color of metallic blue or green.  This means the scales has a high reflectance for blue