丁烯羰基合成戊醛工艺的试验研究与过程开发-化学工艺专业论文.docx

摘 要 戊醛是一种重要的有机合成中间体，它主要是通过丁烯羰基合成制得的。戊 醛可以用于制备戊醇、戊酸、香料等产品。正戊醛经过缩合、加氢可以制备 2- 丙基-1-庚醇（2-PH），2-PH 是制备新型增塑剂邻苯二甲酸二（2－丙基庚醇） 酯（DPHP）的原料，该增塑剂在挥发性、耐油、耐水性等方面都优于传统增塑 剂邻苯二甲酸二辛酯（DOP），是新一代更为安全、环保型的增塑剂，具有广阔 的市场应用前景。 我国戊醛需求量逐年增大，而国内生产量很少，要靠进口才能满足市场需求， 因此，开发戊醛工业化生产技术，满足市场需求，意义重大。 本论文主要通过实验室连续小型试验装置研究了丁烯-1 与合成气经羰基合 成反应生成戊醛的工艺条件，考察了反应温度、压力、催化剂浓度及合成气中 H2 与 CO 的配比等工艺条件对反应过程的影响，获得了较佳的反应工艺条件。 较佳的反应工艺条件为：反应温度：100℃，反应压力：1.5MPaG，催化剂 浓度：金属铑 250ppm，三苯基膦 11～13％（wt%），合成气中 CO 的摩尔浓度 为～35％，丁烯与 CO 的摩尔进料量之比为～1.0。 由此得到的戊醛产品中正、异戊醛的比例为 8～9：1，戊醛产品的选择性（以 丁烯计）≥98％。通过精馏分离得到了纯度≥99％（wt%）的正、异戊醛产品。 在试验研究的基础上，采用化工流程模拟软件完成了年产 1 万吨戊醛生产装 置的工艺计算。所开发的正、异戊醛生产流程包括：丁烯－1 羰基合成生产戊醛、 戊醛蒸发及催化剂回收、正异戊醛精制分离等三部分。为工业生产装置的设计提 供了基础数据。 关键词：正戊醛 羰基合成 试验研究 过程开发 ABSTRACT Valeraldehyde is an important intermediate in organic synthesis; it is mainly produced by Oxo synthesis. Valeraldehyde can be used to produce 1-amyl alcohol, valeric acid and spices etc. By aldolcondensation and hydrogenation, it can also be used for producing 2-n-Propyl-1-heptanol (2-PH) ， a raw material for a new plasticizer-DHDP. DHDP is superior to the traditional plasticizer butyl octyl phthalate (DOP) in volatile, oil resistance and water resistance etc. DHDP is a new kind of plasticizer which is safer and environment-friendliness than the traditional plasticizer and has a wide market prospect. Since the increasing demand for Valeraldehyde year by year in domestic market mainly depends on importing, there is a huge market potential for producing it in China. So, it is significant to develop industrialized production technology of valeraldehyde and to meet the market demand. This paper mainly did a research into the operation conditions of producing valeraldehyde through the synthesis reaction of 1-butene and syngas in lab with continuous small test device and studies the impact made by reaction temperature, pressure, catalyst concentration and the ratio of H2 and CO in syngas on the reaction process. Finally, we get the optimum reaction process condition