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锂离子电池英语论文.doc
Octadecylamine oxide as the template synthesis of lithiated vanadium oxides half opened- nanotubes
Synthesis of Lithiated Vanadium Oxides Half Opened- nanotubes as CathodeMaterials for Lithium Ion Batteries
Junli Sun*
Institute of Science and Research, Department of Science and Research, Chinese People’s Armed Police Force Academy, 220 Xihuan Road, Anci District, Langfang City, Hebei Province (065000), China. Tel (86)316-2067617
Abstract
The lithiated vanadium oxides half opened- nanotubes (HOT) are synthesized by using solid-state and solvothermal reaction with octadecylamine oxide as the template. Transmission electron microscopy (TEM) and scanning electron microscopy (SEM) characterizations show that the synthesized lithiated vanadium oxides nanotubes are half opened and agglomerate. X-ray diffraction (XRD) investigation demonstrates that the synthesized half opened-nanotubes are most consisted of monoclinic phase LiV3O8. Cyclic voltammetry (CV) test indicates that some redox processes are hindered, which is propitious to improve electrochemical performance of LiV3O8 cathode material.
Keywords: electrochemical properties; nano structures; SEM; TEM
Introduction
Nanostructured cathode and anode materials in lithium ion batteries have attracted great attention. This is because they show higher capacity than conventional
*Corresponding author. Tel.: +86-316-2067617; Fax: +86-316-2067613
E-mail addresses:sunjunli@nankai.edu.cn
electrodes composed of the same materials, and the surface area of nanostructured electrodes is much larger than that of conventional electrodes. Vanadium oxides have been widely studied as cathode active materials in lithium rechargeable batteries because of their low cost and high theory capacity [1-6]. Chen W et al. use the template hydrothermal treatment to synthesize V2O5 nanotubes. When they are used as cathode, the resulting cell has shown initial discharge specific capacity of 306mAh g-1 at 3.6-1.5V, which is significantly supe
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