掺钴、锰V2O5薄膜电极的研究-化学专业论文.docxVIP

重庆大学 重庆大学硕士学位论文 英文摘要 II II ABSTRACT Vanadium pentoxide (V2O5) has become a very promising cathode material for lithium-ion batteries because of its advantages like high voltage, high specific capacity, abundant resources, low price and so on. However, the poor structure stability and low conductivity have limited its application in the field of lithium-ion batteries. In this paper, both Co and Mn doped V2O5 thin films were prepared by sol-gel method, which morphologies and electrochemical performances were systematic researched by means of XRD, SEM, TEM, TG-DTA, CV and CP. Firstly, results from XRD, SEM, TEM and TG-DTA showed that the crystal structure of V2O5 has not been changed by doping Co and Mn. However, the V2O5 thin film composed of nanosheet structure roundlike has been converted to rectangle and each nanosheet was composed of nanorods with diameter less than 30 nm. While Co and Mn doped V2O5 thin films are composed of nanosheets with the length of ~500 nm, width of ~170 nm, thickness of ~85 nm, and the length of~ 650 nm, width of ~120 nm, thickness of ~60 nm, respectively. The morphology of doped V2O5 thin film is helpful to reduce the strain during Li+ insertion/de-insertion and prevented the structure changes. Besides, it is beneficial to improve the discharge specific capacity and reduce capacity fading. In addition, some of V atoms are replaced by Co and Mn, resulting the enhancement of electrochemical properties due to the increases of layer gap between a axis and c axis in crystal. And doping gives rise to the generation of oxygen vacancy, reasulting the improvement of materials specific capacity. Secondly, the sol-gel’s concentration and annealing time have effects on the electrochemical performance of V2O5 thin film. It is found that optimum concentration of sol-gel is 0.008 mol/L. Under current density with 400 mA/g, the prepared V2O5 thin film owns a discharge specific capacity of 663mAh/g with 1.09% fading per cycle. The best annealing time is 2