超临界流体改性芳纶力学性能与表面性能研究-材料学专业论文.docxVIP

东华大学硕士学位论文超临界流体改性芳纶力学性能与表面性能研究 东华大学硕士学位论文 超临界流体改性芳纶力学性能与表面性能研究 II II 这一方法为国产对位芳纶纤维的后处理改性及高强高模量化开创了 一条新道路。 （3） 我们发现超临界二氧化碳流体携带 TDI 改性时芳纶纤维的界 面粘合性和表面粗糙度增加，通过改性芳纶纤维布，利用 VARI 及模 压成型分别制备了芳纶-环氧树脂、芳纶-尼龙复合材料，并初步探索 了改性时间及 TDI 用量等因素影响结果，结果发现改性时间 20min， 改性温度 140℃，TDI 用量控制在占体系浓度 0.1%～0.15%之间时两 者改性效果较好。 关键词：对位芳纶，超临界二氧化碳流体，微观控制，TDI，性能改 性 III III STUDY ON MECHANICAL PROPERTIES AND SURFACE PERFORMANCE OF PARA ARAMID FIBER MODIFIED BY SUPERCRITICAL FLUID ABSTRACT Recent years, Para aramid, as a high performance fiber, has been widely focused on in national defense area. It is imminent for domestic para aramid fiber to gain high modulus and high strength. In this paper, supercritical carbon dioxide was used as a swelling agent to swell aramid fiber, as well as a solvent to carry toluene diisocyana (TDI) into the fiber, and then TDI reacted with aramid fiber. The internal and surface of the fiber were successfully modified. The evolution between treating conditions and properties were studied. And the structure and properties were characterized by viscosity method, dynamic mechanical analysis (DMA), scanning electron microscope (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) .Also, we found this method can improve interface properties .The interfacial properties of composites were investigated by making composite material with PA and epoxy resin. In addition, in view of the advantages and disadvantages that exist in the physical and chemical methods, we established a set of physical and chemical usage, and obtained some good results. The main results are as follows: As the supercritical temperature rises, pressure increases and time extends, strength and modulus increases firstly and then decreases. Best conditions of treatment process for GF-1 and Kevlar49 are temperature of 100℃ and 120℃, time of 80 min and 80 min and pressure of 12 MPa and 13 MPa. Structure analysis showed that due to the effect of supercritical CO2, TDI was successfully brought