多形貌Cu或Ag改性SnO2催化剂的制备及其CO低温氧化性能探讨-工业催化专业论文.docx

ABSTRACT nanosheets calcined at the same temperature. The nanorods have an average length of 500 nm and a diameter about 20 nm. Due to the presence of a large amount of mesopores around 4 nm, the surface area of this nanorods is high than that of the Cu-Sn nanosheets. It is revealed by XRD that Cu2+ cations have been incorporated into the crystal lattice of rutile SnO2 to form uniform solid solution. As a result, more active and loosely bounded oxygen species has been formed on the surface of the catalysts, thus improving the CO oxidation activity of the catalysts. Third, 15% Ag-Sn catalysts were prepared by different methods and calcined at 500 oC in air atmosphere. It is founded that the catalysts prepared by co-precipitation and hydrothermal methods show the highest activity, on which CO can be completely oxidized at 170 oC. Interestingly, for 15% Ag-Sn catalysts calcined at 300 oC, the one prepared with co-precipitation method shows evidently improved low temperature activity. Therefore, the Ag/Sn ratio effects on the CO oxidation activity of the catalysts prepared by co-precipitation methods were further studied. It is found that when the Ag content is less than 33%, it is present in the catalysts as Ag2O. As a consequence, these catalysts have better low temperature activity, but the CO conversion increases with the reaction temperature slowly. In comparison, when the Ag content is above 33%, an additional Ag2O2 phase can be detected. Although these catalysts have relatively lower activity at low tempeatures, the CO conversion can light-off quickly to 100% in a very narrow temperature region, which is similar to the reaction behaviors of noble metals. Keywords：Low temperature CO oxidation；Cu-Sn composite oxides；mesoporous nanosheets；mesoporous nanorods；Ag-Sn composite oxides 目录 HYPERLINK \l _bookmark0 第 1 章 绪论 ............................................................................................................... 1 HYPERLINK \l _bookmark1 1.1 研究背景和目的