二氧化碳加氢直接合成二甲醚的研究-应用化学专业论文.docxVIP

ABSTRACT Carbon dioxide is one of the main greenhouse gases. Dimethyl ether (DME) is an important organic chemical product. Hydrogenation of CO2 to dimethyl ether is an effective way to use CO2. It is significance in using exhaust air, eliminating the greenhouse effect, improving the energy structure and promoting the use of renewable resources. Preparation of dimethyl ether by hydrogenation of CO2 is a complex chemical process, including two main steps of CO2 hydrogenation and methanol dehydration. In this paper, thermodynamics, kinetics, reaction mechanism and catalyst research for the synthesis of dimethyl ether from carbon dioxide hydrogenation were reviewed, and the following works were done: Catalyst of CuO-ZnO-Al2O3-Cr2O3/HZSM-5 was prepared by uniform gel method. It was characterized by the methods of XRD、FT-IR and TG/DTA. Catalytic activity of CuO-ZnO-Al2O3-Cr2O3 /HZSM-5 for the synthesis of dimethyl ether from hydrogenation of CO2 was studied in the differential fixed-bed reactor and the effects of the reaction temperature, pressure and the components of catalyst on the catalytic activity were investigated under the conditions of H2 /CO2 = 3(volume ratio) and airspeed = 1600 h-1. The result shows that the conversion of CO2 can be reached to 28.94%, the yield of dimethyl ether is 13.98%, the selectivity and yield of dimethyl ether can reached to 31.76% and 8.76%, respectively under the conditions of pressure at 3 MPa, temperature at 533K，CuO/ZnO = 2/1 (mass ratio) and Cr2O3 =1.5-2.0% (mass percentage). Acid modified polygorskite loaded uniform gel of CuO-ZnO-Al2O3-Cr2O3 was prepared and characterized. It was used for the hydrogenation of CO2 to form dimethyl ether. Acidified polygorskite can effectively accelerate dehydration of methanol to dimethyl ether. Effect of acid concentration and calcination temperature on modified polygorskite, also as the temperature and the pressure on CuO-ZnO-Al2O3-Cr2O3/modified polygorskite on hydrogenation of CO2 to dime