二氧化碳氧化碳的吸附分离-物理化学专业论文.docxVIP

ABSTRACT In r，饵阻t ye缸8， climate change and greenhOuse gas emissiOns have becOme hOt issues. LOw-car协n ecOnOmy is a newωnc叩t prOposed by intematiOnal sOciety， whO re叩Onseω 也at the large number Of fOssil fuels consumed and cOnsiderable C02 emissiOns causing catastrOphic glObal climate change. In the si阳atiOn 由at the energy 户 structure is difficult tO change，cOntrOlling carbOn diOxide emissiOns and develOping lOw-carbOn ecOnOmy are Ones Ofthe mOst impOrtant envirOnmental and en町gy prOb- lems 扭曲e 21st.cen阳ry. Smelting exhaust and automObile exhaust cOntain a lOt Of carbOn mOmOxide and carbOn diOxide. In this paper，the main aim w础 tO fmd an excellent adsorbent 阳 S叩睛 盯ate C02 and CO. This experiment s阳died sev时al different adsOrbnets tO adsOrb C02 at 298k and 0.4 MPa，the flOw rate Of the strearn was k，叩t at 100cm3/min. The bre政t加Ough curves、adsOrptiOn capacity and s叩aratiOn cOefficient w町e Obtain叫- when the coating ratiO Of the TEA mOdified SBA-15 was 1.00，也es叩aratiOn cOeffi- cient calculated is 8.037. We also used ammOniaωlOad On activated carbOn，and fOund ammOnia can enhance its selωtivity fOr C02.，when lOading ratiO w部 0.950， 白e adsorptiOn capacity Of CO was almOst zerO， s叩aratiOn cOefficient between C02 and CO reached up tO 29542. The twO sa:阳rated adsOrbents Of TEA mOdified SBA-15 and activated carbOn 10创叫 arnmOnia were regenerat时， the result shOwed 也at the TEA mOdified SBA15 was difficult tO regenera阳 when purged Or vacuumed at 也e arnbient tempera:阳re. The activated carbOn lOaded ammOnia needed tO be heated tO achieve cOmplete regen町b ‘r tiOn，we fOund the saturatiOn adsOrbent can be regen町ate cOmpletely when at 60.C fOr 30 minutes Or 100.C fOr 15 minutes. ‘ KEY WORDS: adsOrptiOn separatiOn CO2 CO mOdify 目录 第一章文献综述. .? ? ? .? .? ..? ? ..? ? ? .? .? .? .? ..? ? ? ? .? ? .? ? ? ? .? ? ? .? ? ? ? ? ? .? 1 1.1 C02分离的重要性…………........…………川......…......，...…........… 1 1.1.1 租室效应及其危害............………………......…...............… .........1 户 1.1.2 CO2 的特性、来源及用途....…