二氧化钛分子团簇的合成机理及其光催化性能研究-化学专业论文.docxVIP

Titania clusters can be completely degrades N719, but nano crystal cannot. So,molecular cluster performance of photocatalytic oxidation of N719 is better than nanocrystalline. Peptizing time and peptizing acidityaffect photocatalytic oxidation N719 larger, peptizing temperature and reactant concentration have little effect on it. Titania clusters can photocatalytic reduction of Cr (VI) in the sunlight, but nano crystal cannot. Titanium dioxide molecules cluster light catalytic reduction of Cr (VI) only needs 10 min under ultraviolet light, nanocrystalline for 2h. Peptizing time, peptizing acidity, concentration of sol have great effect on photocatalytic reduction of Cr (VI) great. When peptisation is omplete, acidity is 0.025mol/L, the sol concentration is 1.03g/L, the photocatalytic reductioneffect is the best. Key word: Titanium dioxide molecule clusters, photocatalytic oxidationN719 , photocatalytic reduction Cr(Ⅵ) 目 录 中文摘要...............................................................................................................................I 英文摘要............................................................................................................................. II 1 绪 论 ........................................................................................................................... 1 1.1 研究背景 ........................................................................................................................... 1 1.2 半导体二氧化钛的结构与光催化性质 ........................................................................... 1 1.2.1 二氧化钛结构 ......................................................................................................... 1 1.2.2 二氧化钛光催化原理 .............................................................................................. 3 1.3 影响二氧化钛光催化活性的因素.................................................................................... 4 1.3.1 二氧化钛的晶型 ...................................................................