二硫化锡及其与石墨烯复合材料的可控制备和光催化性能研究-材料工程专业论文.docxVIP

ABSTRACT As an ideal green technology for solar-to-chemical energy conversion and environmental purification, semiconductor photocatalysis has been paid increasing attentions in recent years. The surface structure of a photocatalytic material plays a crucial role in its photocatalytic activity because the photocatalytic reaction takes place only when the electrons and holes are available on the surface. As an important layered structure material, SnS2 possesses interesting optical, electrical, gas sensing and catalytic properties, and has attracted much attention for its applications in solar cell, Li-ion battery anode material, gas sensing and catalytic material. So far, however, the influence of surface structure of SnS2 on the photocatalytic performance has been studied rarely. In this thesis, different morphologies of SnS2 with high visible light photocatalytic activity were synthesized via solvothermal method. Photocatalytic property and photoelectrochemical performance of the as-prepared samples were evaluated. First principle theoretical calculation and molecular dynamic simulation were employed to study the electronic structure and the surface property of SnS2, respectively. Moreover, to suppress recombination between photoexcited electrons and holes, we developed a one-step hydrothermal method to synthesize SnS2/graphene composites, and the photocatalytic degradation of methyl orange was conducted. The main results are as follows: A solvothermal method was used to synthesize sheetlike and flowerlike SnS2 by using SnCl4·5H2O and TAA as the precursors, respectively. Different kinds of solvents were added for obtaining different morphologies of SnS2. XRD analysis, SEM and TEM observation indicated that the exposed crystal planes of sheetlike SnS2 and flowerlike SnS2 were {001} and {010}, respectively. While the valence band XPS spectra show that the VB maximum of sheetlike SnS2 is identical to that of flowerlike SnS2, UV-vis absorbtion spectra demonstrate tha