3-乙基-3-烯丙基甲氧基氧杂环丁烷的合成与其应用-研究.pdf

ABSTRACT ABSTRACT The paper reported the synthesis of a novel oxetane compound 3-Ethyl- 3-allyloxymethyl oxetane, and the study of its properties in radical, cationic and hybrid-type UV-curable system with 3-ethyl-3-allyloxymethyl oxetane as the reactive diluent. The details of research are as follows: Firstly, 3-Ethyl-3-allyloxymethyl oxetane was synthesized by utilizing 3-Ethyl-3-hydroxymethyl oxetane(EHO) and allyl bromide as raw materials, tetrabutylammonium bromide as phase transfer catalyst, together with the aqueous solution of potassium hydroxide. The effects of feed ratio of the raw materials, amount of catalyst, reaction temperature and reaction time on the yield were researched, and the best reaction conditions were as follows: n(EHO):n(allyl bromide)=1:1.4, m(EHO):m(tetrabutylammonium bromide)=23.2:1, the reaction temperature was 0 ℃, the reaction time was 24h. Secondly, the novel reactive monomer was introduced in the cationic-type UV-curable materials. The results showed that: the novel reactive monomer has a good effect on diluting epoxy, and the best mass fraction of the photoinitiator was 5%; when m(epoxy resin ):m(the new reactive monomer)=4:1, cured-material exhibits good mechanical properties, thermal properties, flexibility, adhesion, water resistance and acid resistance. Thirdly, the novel reactive monomer was introduced in the radical-type UV-curable materials. The results revealed that: The preferred charge ratio of photoinitiator was 4%, and when the mass fraction of t