简单廉价方法可控合成球状介孔二氧化硅材料-国家级大学生创新创业.PDFVIP

简单廉价方法可控合成球状介孔二氧化硅材料 西南科技大学 董雪，王怡，旦辉，洪志浩，宋坤建，鲜强，丁艺 （西南科技大学国防科技学院，四川绵阳，621010 ） 《Materials Letters》2017 丁艺 副教授 中文摘要:以廉价粉石英作为硅源，P123 为模板剂，不采用任何添加剂，仅通过调节盐酸浓度简单可控合成球状介孔 SBA-15 材料。研究了盐酸浓度对所制备介孔二氧化硅材料的形貌及微观结构的影响规律。发现盐酸浓度对材料的形貌及介 观结构具有较大影响。随着盐酸浓度的增加，介孔SBA-15 形貌由棒状向球状转变。当盐酸浓度为4 M 时，介孔SBA-15 材 料为1-4 μm 大小的球形颗粒。结果显示以粉石英为硅源，通过调节盐酸浓度可成功合成球状介孔SBA-15 材料。 英文摘要：A facile route is demonstrated to synthesize mesoporous SBA-15 silica spheres using powder quartz as an inexpensive silica source and P123 as a structure-directing agent, no other additives were used. The effect of hydrochloric acid concentration on the morphology and microstructure of mesoporous silica materials was investigated. It was found that the morphology and structural order of the samples were strongly influenced by the HCl concentration. The morphology of SBA-15 silica transfers from rod-like to sphere-like with increasing HCl concentration. As HCl increased 4 M, the morphology of SBA-15 silica is sphere-like particle with size ranging from 1-4 µm. The results show that the spherical mesoporous SBA-15 material can be successfully synthesized by adjusting the concentration of hydrochloric acid when powder quartz as silica source. 关键词: 多孔材料、介孔SBA-15、球形、盐酸浓度、粉石英 一、引言 [1] 自介孔材料被发现以来，因其具有优异的特性而备受关注 。介孔 SBA- 15 由于比表面积大，形貌可 控，均一的孔道分布，孔径大小及长度可调，孔壁厚且水热稳定性高等特性使其在催化、分离、生物医药 [2-7] 及纳米材料等领域有广泛的应用前景 。近年来，国内外研究表明介孔材料的应用性能不仅取决于其内部 [8-10] [11] 孔道结构，还受控于其形貌、颗粒尺寸等 。在早期的研究中，赵东元等 首次成功在酸性环境中，合