porous reduced graphene oxide sheet wrapped silicon composite fabricated by steam etching for lithium-ion battery application：用于锂离子电池用蒸汽腐蚀法制备的多孔氧化石墨烯复合材料.pdf

Journal of Power Sources 286 (2015) 431 e437 Contents lists available at ScienceDirect Journal of Power Sources journal homepage: /locate/jpowsour Porous reduced graphene oxide sheet wrapped silicon composite fabricated by steam etching for lithium-ion battery application H. Tang a, J. Zhang b, Y.J. Zhang a, Q.Q. Xiong a, Y.Y. Tong a, Y. Li a, X.L. Wang a, C.D. Gu a, J.P. Tu a, * a State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Provence, and School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China b Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, China h i g h l i g h t s A novel preparation method is fabricated by steam etching of Si/rGO aerogel. This method is easy to handle and exhibited excellent performances. The in-situ TEM verifies the well-retained integrity of electrode in the substrate. a r t i c l e i n f o a b s t r a c t Article history: A novel of Si/porous reduced graphene oxide (rGO) composite is fabricated by steam etching of Si/rGO Received 1 March 2015 aerogel. The rGO sheets with nano-holes build a unique three-dimensional porous network and can Received in revised form encapsulate the Si nanoparticles. The porous structure of Si/rGO composite can reduce the transfer 28 March 2015 distance of Li ions and restrain the aggregation and destruction of Si particles.