新型固相萃取-高效液相色谱检测饮用水中的邻苯二甲酸脂类物质.PDF

6 7 Vol. 6 No. 7 2015 7 Journal of Food Safety and Quality Jul. , 2015 * 何金兴, 张 伟, 崔一笑 , 刘宝发, 马 雪 (, 250353) 摘 要: 目的 - 方法 3- , , , , , 结果 : (96:4, V:V); 20 min; 230 nm; 1.0 mL/min; 30 ℃; 20 μL , DMPDBPDIDP 0.5~100 mg/L, DCHPBBPDEHP 0.5~25 mg/L, DEP 0.5~10 mg/L; 7 0.18 μg/L~1.86 μg/L , 6 1.18%~5.20%, 63.5%~108.4%结论 关键词: ; ; ; ; Determination of phthalates in drinking water by new solid-phase extraction coupled with high performance liquid chromatography * HE Jin-Xing, ZHANG Wei, CUI Yi-Xiao , LIU Bao-Fa, MA Xue (School of Food Science and Engineer, Qilu University of Technology, Jinan 250353, China) ABSTRACT: Objective To establish a method for the determination of 7 phthalates in drinking water developed based on solid-phase extraction coupled with high performance liquid chromatography (SPE-HPLC) technology. Methods The high selectivity material was synthesized by 3-aminopropyltriethoxysilane (APTES)as the functional monomer, tetraethoxysilane (TEOS) as the crosslinking agent, and 0.1 mol/L acetic acid as the initiator. The characteristics of preparative material were selective adsorption, and co