毛细管气相色谱法测定酱油中丙酸盐的不确定度评定-食品安全质量.PDF

5 9 Vol. 5 No. 9 2014 9 Journal of Food Safety and Quality Sep. , 2014 刘莉萍* ( , 518055) 摘 要: 目的 方法 , , 结果 0.75 g/kg , 0.06 g/kg (k=2) , 结论 , , 关键词: ; ; ; Evaluation of uncertainty for determination of propionate in soy sauce by capillary gas chromatography * LIU Li-Ping (Shenzhen Polytechnic, Shenzhen 518055, China) ABSTRACT: Objective To evaluate the uncertainty for the determination of propionate in soy sauce by capillary gas chromatography. Methods The sources of uncertainty in the process of determination were analyzed, a mathematical model of uncertainty evaluation was established and the effect of measurement uncertainty was assessed. Results The expanded uncertainty was 0.06 g/kg (k=2) with 0.75 g/kg of the content of propionate. The major sources of measurement uncertainty included the sample recovery, the calibration of standard curve and preparation of standard solution. Conclusion It is necessary to control experimental conditions, including guaranteeing the sample recovery, the linearity of standard curve, and the testing results accurately. KEY WORDS: capillary gas chromatography; propionate; soy sauce; uncertainty [1]: 1 引 言