四川白玉铜精矿开发利用研究.doc

PAGE doi：10.3969/j.issn.1007-7545.2014.06.007高铅锌复杂黝 doi：10.3969/j.issn.1007-7545.2014.06.007 王成彦，尹飞，陈永强，阮书锋 (北京矿冶研究总院，北京 100160) 摘要：某高铅锌复杂黝铜精矿富含铜、银，还含有铅、锌、锑等有价金属。通过现有类似工艺方案的比较和试验验证，推荐采用“半硫酸化焙烧—硫酸浸出铜、锌—盐酸氯盐浸出银、锑—次氯酸钠氧化浸金—碳铵转化回收铅”的综合处理工艺回收有价元素。验证试验结果表明，铜、锌、铅的总回收率均大于95%，银、金、锑的总回收率分别大于98%、94%和90%。该工艺中各操作单元大多已有工业应用的实践经验，工业化简单。 关键词：铜精矿；黝铜矿；沸腾焙烧；半硫酸化焙烧；综合回收 中图分类号：TF81；TF832 文献标志码：A 文章编号：1007-7545（2014）06-0000-00 Process Selection of Comprehensive Treatment for Complex Tetrahedrite Concentrates with High Pb-Zn Bearing WANG Cheng-yan, YIN Fei, CHEN Yong-qiang, RUAN Shu-feng (Beijing General Research Institute of Mining and Metallurgy, Beijing 100160, China) Abstract: Complex tetrahedrite concentrates with high Pb-Zn bearing are rich in copper, silver, as well as valuable metals such as lead, zinc, antimony. Based on comparing the existing similar processes scheme and test verification, the following comprehensive process was recommended to recover valuable element, i.e., half-sulfating roasting, leaching copper and zinc with sulfuric acid, leaching silver and antimony with hydrochloric acid and chlorine salt, oxidizing leaching gold with sodium hypochlorite, lead recovery via ammonium carbonate transformation. The results of verification experiment show that total recovery rate of copper, zinc and lead is 95% above, total recovery rate of silver, gold and antimony is 98%, 94% and 90% above respectively. This process is easy to be commercialized as most of its operating units have been practiced in industry. Key words: copper concentrate; tetrahedrite; fluidized roasting; half-sulphating roasting 四川省甘孜藏族自治州白玉县境内的呷村银多金属矿是一座品位高、易开采、难分选的含银、铅、锌、铜、金等多种金属的复杂矿床，属多金属大型富矿床。该矿床的铜矿物主要为黝铜矿，铜、银、锑主要赋存于黝铜矿中，锌、铅主要以闪锌矿和方铅矿形态存在。根据该矿物特点，仅靠选矿手段，难以生产出合格的单独铜、铅、锌精矿产品，铜精矿产品中锌和铅含量较高[1-2]。北京矿冶研究总院以成熟的沸腾焙烧技术为基础，对以黝铜矿为主的复杂铜精矿处理和伴生有价元素的综合回收进行了系统的试验研究，取得了较好的技术经济指标[3]。本文主要结合现有相关冶炼工艺特点，并通过验证试验，为该矿的综合处理选择较佳的冶炼工艺。 1 矿物组成及主要元素赋存状态 呷村高铅锌复杂黝铜精矿富含铜、银，此外还含有铅、锌、锑等有价金属。其中金、银品位分别为1.92 g/t和2 845 g/t，化学分析结果（%）：Cu 1