煤热解过程中含氮气相产物转化规律的试验研究PDF.PDF

36 2 V o.l 36 No. 2 2008 4 Jour al of Fuel Chem istry a d Tech o logy Apr. 2008 : 2008) 0213405 刘海峰, 刘银河, 刘艳华, 车得福 ( , 710049) : , 500 700 900 1 100 , , NO H CN NH 3 , N , , 2 ; , , N , HCN NH 2 3 : ; ; H CN; NH ; N 3 2 : X 131. 1 : A E xpermi enta l investigation on the conversion of n itrogenous gas products during coal py ro lysis L IU Haife g, LIU Y i he, L IU Y a hua, CHE D efu ( State Key Laboratory ofM ultiphase flow i Pow er E gi eeri g, X ia Jiaoto g U iversity, Xia 710049, Ch i a ) A bstract: The co versio of itroge ous gas products duri g coal pyrolysis w as i vestigated i the drop tube reactor. Four raw coals a d wt o dem i eralized coals have bee used to pyrolyse at 500 , 700 , 900 a d 1 100 . The pyrolysisresults i d icate that the yields of N a d NO precursors, such asHCN a d NH , i crease 2 3 w ith i creased tem perature. The coal type has sig ifica t effect o the yield of itroge ous gas products. For low ra k coal sample, the co versio ratio of fuel itroge is h igher. The most of fuel itroge i h igh ra k coals is built i to co de sed arom atic structures to form CharN. The m i eral substa ces i coal prom ote the co versio of fuel itroge to N , but they suppress the co versio of fuel itroge to HCN a d NH . 2 3 K ey w ords: coal; pyro lysis; HCN; NH ; N 3 2