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铜基合金在500-800℃下之高温硫化行为研究
483 496200512
Journal of Chinese Corrosion Engineering, Vol.19 No.4, PP. 483~496 (2005)
500-800
High-Temperature Sulfidation Behavior of Cu-Base Alloys
P. C. Chen, C. C. Lee, W. Kai*
(Cu-25Zn Cu-25Zn-5Al at%) 500 ~
800H /H S
2 2
Cu-25Zn-5Al
Cu-25Zn
Cu-25Zn (Cu S) (ZnS)
2
Cu-25Zn-5Al (Cu S) (ZnS)
2
(CuAlS )
2
Cu S ZnS CuAlS
2 2
ABSTRACT
High-temperature sulfidation behavior of two Cu-base alloys (containing Cu-25Zn and Cu-25Zn-5Al,
in at%) over the temperature range 500 ~ 800 in H /H S gas mixtures was studied. In gerneral, the
2 2
sulfidation kinetics of both alloys followed the parabolic rate law at all temperatures, and the corrosion rate
constants increased with increasing temperature. The sulfidation resistance of the ternary alloy is much
better than the binary alloy. The scales formed in H /H S gas mixtures were complex and heterophasic,
2 2
consisting of an outer layer of Cu S and an inner layer of ZnS for Cu-25Zn, and of an outer layer of Cu S
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