壳聚糖本科毕铭业论文.docVIP

PAGE 1 铅离子印迹聚合物的制备表征及其吸附性能研究 农药学专业 王东方 指导教师 张炜 摘要：水中重金属离子污染问题愈发严重，为了解决这个问题，用表面印迹技术以铅离子为模版分子，以壳聚糖为功能单体，采用分子印迹技术，加入交联剂环氧氯丙烷，合成了铅离子印迹的交联壳聚糖。用红外光谱对铅离子交联壳聚糖进行了结构表征，探讨壳聚糖对铅离子的吸附机理。用原子吸收分光光度法对印迹聚合物的最大吸附量进行了研究，结果表明，所合成的模板交联壳聚糖分子印迹聚合物对铅离子具有良好的吸附性。研究了不同条件下交联壳聚糖对铅离子吸附性能,结果表明，当溶液pH为4.5时，交联壳聚糖对溶液中铅离子的吸附效率较高。吸附在交联壳聚糖上的铅离子可用0.1mol/L的EDTA溶液洗脱，该方法的铅离子洗脱率能够到达82.73％,洗脱率较高，可用此方法进行印迹聚合物的洗脱。对印迹聚合物的选择性吸收进行研究，研究表明，印迹聚合物对铅离子的选择性好，对有益金属离子吸附性小，能用于水溶液中除去铅离子。 关键词：分子印迹聚合物 壳聚糖 铅 环氧氯丙烷 原子吸收分光光度法 Lead ions, molecularly imprinted polymer preparation of representation and its adsorption properties Student majoring in pharmacy Wangdongfang Tutor Zhangwei Abstract：Water pollution has become more serious problems of heavy metal ions, in order to solve this problem,surface imprinting technology to lead ions as a template molecule, chitosan as a functional monomer, especially epichlorohydrin as a crosslinking agent, synthesis of lead ions imprinted crosslinked chitosan.To characterize the structure of the synthesized product using infrared spectroscopy on crosslinked chitosan to investigate the adsorption mechanism of chitosan for lead ions.We can use the atomic absorption spectrophotometry to study the maximum adsorption capacity of imprinted polymer .The results showed that the synthetic template cross-linked chitosan molecular imprinted polymer has a good adsorption of lead ions.Research in different conditions by crosslinking the chitosan lead ions adsorption performance,research in different conditions by crosslinking the chitosan lead ions adsorption performance, the results show that, when the solution for pH 4.5 ,crosslinking chitosan adsorption of lead ions has higher efficiency.The lead ions has been adsorption by crosslinking chitosancan ,we can use the 0.1 mol/L EDTA solution to elution the lead ion, the elution rate of this method can reach with 82.73%, elution rate is very high, we can use this method to elution the lead ion in the molecularly imprinted polymer. Studi