电絮凝技术处理油田污水的影响因素实验研究.docxVIP

电絮凝技术处理油田污水的影响因素实验研究 　　摘 要：针对油田乳化液的水质特性，用电絮凝方法对配制的含油污水进行实验研究.首先分析极板间距、溶液初始pH值及NaCl含量对除油率的影响，确定实验参数.继而，实验研究电絮凝装置中竖直方向上典型的三层溶液，考察不同?流密度下除油率随时间的变化规律，比较三层除油率的特性曲线.发现A层去除效果最快最好，B层比C层处理效果差.在电解前4 min，电流密度为150 A/m2时，A层除油率占其总效率的%.从平均成本和三层除油率综合判定，电解16 min，电流密度在100 A/m2时，电絮凝装置中整体处理效果最好.　　关键词：电絮凝；含油污水；流场；实验研究　　中图分类号：X741 文献标志码：A　　Experimental Study on Influence Factors of Oil Field WastewaterTreatment by Electrocoagulation　　LIU Yang， LI Yuxing， JIANG Wenming， CHEN Mingcan， YANG Jie， XU Chunwen　　　　Abstract：Aiming at the characteristics of oil field sewage， the electrocoagualation process was used for the experimental study on preparation of oily waste water. The effects of electrode distance， initial pH and NaCl content on oil removal rate were analyzed， respectively， and the influence parameters were obtained. The flow field experiment was firstly carried out . Then， the solution was divided into representative of three layers in the vertical direction， while the changes of oil removal rate under different current density with time were examined， and the characteristic curves of the three layers with the oil removal rate were compared. The results showed that oil removal rate of A layer was the fastest and best， while the oil removal effect of B layer was worse than that of C layer. When electrolysis time was 4 min and current density was 150 A/m2， the oil removal effect of A layer accounted for % of total efficiency. Considering the average cost and oil removal rate of three layers， the overall treatment was the best in EC reactor when electrolysis time was 16 min and current density was 100 A/m2.　　Key words：electrocoagulation；oily waste water；flow field；experimental study　　随着油田开采规模的不断扩大，我国大部分油田已经进入高含水开发中后期[1]，采出油中含水量不断增加，如果这些水不经处理直接排放到环境中，不仅严重污染环境，破坏生态平衡，还会造成水资源浪费，因此，开展含油污水处理技术的研究对实现环境保护、节能减排具有重要意义.但在油田开采中，添加了大量的表面活性剂，油珠严重乳化[2]，微小油珠很难凝聚，增加了油水分离的难度，常规的方法很难达到回注或排放标准，因而迫切需要一种高效环保的污水处理技术.电絮凝与其他水处理技术相比具有装置紧凑、操作简便、处理效果好、无二次污染等优点，随着我国环保战略的实施，该技术越来越受到重视[3-4].　　针对含油污水，国内外研究