碳热还原氮化高钛渣合成TiNβ′-Sialon导电陶瓷粉体-中国科技论文在线.PDFVIP

碳热还原氮化高钛渣合成TiN/β′-Sialon导电陶瓷 粉体 姜 涛， 李 江， 薛向欣， 巫俊斌 （东北大学材料与冶金学院，辽宁省高校硼资源生态化综合利用技术与硼材料重点实验室， 辽宁 沈阳 110004） 摘 要： 以高钛渣、高铝矾土熟料、硅灰和炭黑为原料，采用碳热还原氮化法合成 TiN/β ′-Sialon 导电陶瓷粉体。利用 XRD，SEM 和 EDS 检测手段研究了合成温度、恒温时间对反 应过程的影响，并探讨了合成机理。结果表明：合成温度、恒温时间对反应过程影响显著。 1400℃恒温 2h时，β′-Sialon含量达最大，是最佳的工艺参数。此时β′-Sialon晶粒多 呈长柱状，TiN为细小粒状。合成过程中 SiO的挥发导致试样较大的质量损失，且随合成温 度升高和恒温时间延长而增大。 关键词： 高钛渣；碳热还原氮化；TiN/β′-Sialon；导电陶瓷；粉体 中图分类号：TQ174.75 文献标识码：A 文章编号： Synthesis of Electroconductive Ceramic Powder of TiN/β′-Sialon by Carbothermal Reduction-nitridation of High Titania Slag JIANG Tao, LI Jiang, XUE Xiang-xin, WU Jun-bin (School of Materials Metallurgy, Northeastern University, Liaoning Key Leboratory for Ecologically Comprehensive Utilization of Boron Resources Materials, Shenyang 110004, China. Correspondent:JIANG Tao, E-mail:jiangt@) Abstract: TiN/β′-Sialon electroconductive ceramic powder was synthesized by CRN (carbothermal reduction-nitridation) with high-titania slag, bauxite chalmette, silicon fume and carbon black as starting materials. The influences of various reaction parameters such as temperature and holding time at the top temperature on the reaction process were studied by XRD, SEM and EDS, as well as the synthesis mechanism. The results showed that the synthetic reaction process of TiN/β′-Sialon powder is greatly affected by the holding time and temperature. The content of β′-Sialon in the sample becomes maximum at 1400℃ for 2hr and these process parameters are regarded as the best during synthesis. At that moment most of