介孔炭电极材料的制备及其性能研究化学工程与技术专业论文.docx

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 - - II - Abstract Activated carbon is a good material which has been used in commercial electrochemical capacitors. Although it has plenty of advantages such as: low price, stable cycling performance, it’s specific capacitance is low and it’s capacitor decline rapidly at a high discharge current. In this paper we propose solution to the two shortcomings of activated carbon. Esoporous carbons were prepared by an inverse replica technique. we prepared mesoporous carbons by using mesostructured MCM-41, SBA-15, MCM-48 silica materials as templates whereas phenolic resin was the carbon precursor. The results of X-ray diffraction and BET surface area measurement show that SBA-15 templated mesoporous carbon is highly ordered mesoporous carbon. MCM-41 templated mesoporous carbon has a large number of mesoporous but it also has a certain amount of microporous and become a relatively high surface area carbon irregular. MCM-48 templated mesoporous carbon has narrow pore size distribution, the vast majority of the mesoporous is between 1nm to 3nm, but when it is time to remove the template crystallography symmetry droped, rather than reverse recovery of MCM-48 template. The result of electrochemical test such as cyclic voltammetry, electrochemical impedance spectroscopy, constant current charge-discharge test, etc. demonstrate that preparation mesoporous carbon materials are better than the commercialization activated carbon of the rate characteristics and capactiance. 500 cycle tests show that mesoporous carbon materials have a better cycle performance. One modification is that the mesoporous carbon and the commercialization activated carbon is oxidized in concentrated nitric acid at 100 °C. And the other modification is that carbon was oxidized in concentrated sulphuric acid at 100 °C, then oxidized in concentrated nitric acid at 100 °C. X-ray diffraction is used to study the structure of SBA-15 templated mesoporous carbon. The results show tha