纳米二氧化硅表面功能化及其表征-仲恺农业工程学院学报.PDF

仲恺农业技术学院学报, 20 (1):36～41, 2007 Journal of Zhongkai University of Agriculture and Technology :1006-0774 (2007)01-0036-06 (仲恺农业技术学院化学化工系, 广东 广州510225) :, (glycidyl methacrylate, GMA), , , 、 、 ., . (FT-IR)、 (TGA)、 (XP )、 (TEM). :;; :TQ325.7 　　　　　:A Surface functionalization and its characterization of SiO2 nanoparticles ZHOU Hong-jun (Department of Chemistry and Chemical Engineering, Zhongkai University of Agriculture and Technology, Guangzhou 510225, China) Abstract :iO2 nanoparticles were functionalized with surface grafting poly glycidyl methacrylate (PGMA)by free-radical polymerization.The effects of monomer concentration, initiator concentration, reaction tempera- ture, reaction time on graft polymerization were studied in details.It was found that the grafting degree for the nanoparticles can be controlled by changing monomer concentration.FTIR, TG, XP , TEM were used to characterize the modified nano-silica. Key words:nano-silica;functionalization;characterization 　　, [1-2] ., , ., ., [3-5] , .Tsubokawa , . , 、、 、 , , . (Glycidyl methacrylate, GMA), [6] , , -COOH, -NH2 -OH , (Poly glycidyl methacrylate, PGMA), . PGMA , . γ- (KH570), , , . 　 :2006-10-18 : (G2360244). : (1975-), , , , . 1 : 37 , . 1　 1.1　 2 3 (iO ), DEGU A , 12 nm, 200 m /g, 2.2 g/cm ; 2 (GMA):, ;KH570:γ- , ; (AIBN ):, , . 1.2　 Nicolet Nexus 670 FT-IR ;Netzsch TG-209 ; JEO-2010 ;VG E CALAB MK ⅡXP . 1.3　 1.3.1　纳米 iO2 的偶联剂处理　 500 mL , 10 g 120 ℃ 12 h