浆料催化精馏新工艺制异丁烯的研究-化学工程专业论文.docxVIP

中文摘要本文提出了叔丁醇一一浆料催化精馏脱水的新工艺，浆料催化精馏所用 中文摘要 本文提出了叔丁醇一一浆料催化精馏脱水的新工艺，浆料催化精馏所用 的催化剂为粒径很小的微粒或超微颗粒，使其与液相形成浆料在塔内流动， 并循环使用。本文采用细粉状的强酸性阳离子交换树脂做催化剂，考察了这 一新工艺的可行性。 考察了催化剂浓度、操作压力、迸料组成和进料流量等条件对浆料催化 精馏过程的影响。实验结果表明：提高催化剂浓度会提高叔丁醇的转化率； 进料组成变化对叔丁醇转化率的影响很小；当压力由O．2MPa升至0．25MPa 时，转化率略有升高，当压力超过0．25MPa以后，随着压力的增高，叔丁醇 的转化率逐渐降低；进料流量对叔丁醇转化率的影响十分明显，进料流量减 小会使叔丁醇的转化率得到明显提高。叔丁醇的转化率可达到99．99％。 采用平衡级模型，应用Aspen Plus软件对实验过程及各操作参数对过程 的影响进行模拟，模拟结果与实验结果吻合的较好。结果揭示了过程各参变 量在塔中的变化规律，为工艺及塔的设计提供依据。 最后，对浆料催化精馏应用到离子交换树脂法制异丁烯的新工艺进行了 探讨，与普通的催化精馏相比，浆料催化精馏具有不需要制作催化剂元件、 不需要停车更换催化剂、催化剂效率高和易于工业化生产等优点，具有迸一 步研究与开发的前景。 关键词： 浆料催化精馏： 转化率； 叔丁醇； 异丁烯 ABSTRACTA ABSTRACT A novel technology of dehydration of tert-butyl alcohol-·一slurry catalytic distillation was studied in this paper．A fine particulate catalyst was slurried in one of the reactant streams and fed into a distillation column reactor and was recycled．In this paper,the feasibility of slurry catalytic distillation process was studied with the fine particles of acid cation exchange resin as catalyst． The effects of catalyst concentration，operating pressure，feed composition and feed flow on the conversion ratio of tert-butyl alcohol were experimentally investigated．The experiment result indicated that increase of catalyst concentration Can improve the conversion ratio of tert—butyl alcohol，that tile varieties of feed composition had few effects on the conversion ratio of tert—butyl alcohol，that with increase of operating pressure from O．2MPa to 0．25MPa．the conversion ratio improved a little，but when operating pressure exceeded O．25MPa，the conversion ratio decreased gradually with increase of operating pressure，and that feed flow had the obvious effect on the conversion ratio of tert—butyl alcohol and the conversion ratio improved obviously with the decrease of feed flow．The highest conversion ratio often—butyl alcohol Can come up to 99．99％． Based on the equilibrium stage model，slurry catalytic distillation process and the effects of operation parameters on slurry catalytic