金属纳米颗粒高分子杂化材料的研究-高分子化学与物理专业论文.docxVIP

1一趸摘耍中文摘要 1一趸摘耍 中文摘要 无机金属／局分子杂化材料由于其出色的性能， ‘直足人们研究的热点，有 很高的学术价值和广泛的应用前景。 本文采用“原他法”制备了金属纳米颗粒／高分了杂化自组装薄膜。本文用 3．0代聚酰胺一胺型树状高分子(PAMAM)作为聚阳离了，磺化聚苯乙烯和聚丙 烯酸作为聚阴离子，通过静电作用进行层．层自组装，制备了高分了薄膜。将金 属银离子负载在薄膜中，通过氢气还原，在薄膜中制备了金属银纳米颗粒。用形 态仪和紫外：可见光谱研究了薄膜厚度的规律增长和纳米金属颗粒的形成。透射 电镜结果证明了薄膜中金属的形态为纳米颗粒。此外还在导电玻璃上制备了金属 纳米颗粒／高分子杂化自组装薄膜，循环伏安法测试研究了金属纳米颗粒在薄膜 中的行为状态。 本文还用一种新的方法制备包含金属纳米颗粒的高分子空心纳米胶囊。以表 面修饰有树状高分子的纳米二氧化硅球为模板，通过吸附，还原在二氧化硅球表 面制备了金属纳米颗粒。用聚电解质磺化聚苯乙烯钠和聚丙烯胺通过层一层自组 装的方法包裹在二氧化硅球的外部。除去内部的二氧化硅球模板，制备得到了囊 壁中包含金属纳米颗粒的空心纳米胶囊。透射电镜证明了胶囊的特殊结构。 我们将上述材料都用于催化小分子有机反应。在对硝基苯酚还原的反应中， 显示了很好的催化性能。 关键词：树状高分子、层一层自组装、薄膜、纳米胶囊、金属纳米颗粒、催 化 Metal Metal nanoparticles／polymer composites materials based on assembled polyelectrolyteldendrimer Abstract Inorganic nanoparticles／polymer composites materials have generated great interest doe to their desired properties and potential applications． Silver nanocomposite multilayer films were prepared throu曲the in—situ method． Multilayer thin films through the sequential electrostatic deposition of a positively charged third generation poly(amidoarnine)PAMAM dendrimer and negatively charged poly(styrenesulfonate)(PSS)and poly(acrylic acid)(PAA)were utilized as nanoreactors for the formation of silver nanoparticles．The silver ions were prenrganized in the layer-by—layer(LBL)films composed of PAMAM dendrimers， and subsequently reduced wit}l hydrogen to prepare the silver nanoparticles．The UV-vis spectrmn and profilometer were used to characterize the regular growth of bilayers．The TEM images indicated the synthesis of the silver nanopartiqles in the multilayer films．The silver nanocomposite LBL films were also constructed on the ITO-glass and investigated by the cyclic voltammetry(CV)．The silver nanopartieles in the multilayer films had a more negative redox potential． A novel route to fabricate metal nanoparticles composites hollow capsules was introduced．The polyamidoamine(PAMAM)dendritic polymer—modified silica nanoparficles were used as templating cores．The modified silica n