黄铜矿精矿的酸性热压氧化提铜工艺研究.PDF

23 4 矿　冶　工　程 Vol.23 №4 200308 MININGAN METALLURGICAL ENGINEERING August 2003 1 2 1 1 1 1 1 1 谢洪珍, 黄怀国, 江　城 , 林鸿汉, 孙　鹏, 罗吉束 , 邹来昌, 陈景河 (1., , 364200;2., 361006) 　:, 、、。 : 110 ～ 115 ℃;NaCl 、、Cu 。 0.45 MPa, 110 ℃, 4 h, NaCl 40 g L, H SO 110 g L, 5 ∶1, 750 r min , 2 4 Cu 98%。 4 ∶1, 2 kg t, 24 h, , 85%。 :;; A Study on Copper Extraction from Chalcopyrite Concentrate by Acidic Hot-pressure Oxidation 1 2 1 1 1 1 1 XI Hong-zhen , HUANG Huai-guo , JIANG Cheng , LIN Hong-han , SUN Peng , LUO Ji-shu , ZOU Lai-chang , CH N 1 Jing-he (1.Fujian Zijin Research Institute of Mining and Metallurgy , Fuj ian Zijin Mining Industry Co, LTD, Shanghang 364200, Fujian, China;2.Xiamen Zjiin Science and Technology Co, LTD, Xiamen 361006, Fujian, China) Abstract:The paper deals with copper extraction from chalcopyrite concentrate by acidic hot-pressure oxidation.The authors discuss the influence of such technical parameters as initial acid concentration, leaching temperature and leaching time etc, on copper leaching rate.The results have shown that the optimum leaching temperature ranges from 110 ℃to 115 ℃.The leach- ing rate of copper can be increased by increasing initial acidity, concentration of NaCl, partial pressure of oxygen and reaction time.When the partial pressure of oxygen is 0.45MPa, the temperature is 110 ℃, the leaching time is 4 h, the initial con- centration of NaCl is 40 g L, the initial concemtration of H SO is 110 g L, the L S ratio is5 and the agitation velocity is 750 2 4 r min and the leaching rate of copper is up to 98%.Under oscillating cyanidation condition and at L S ratio of