环境水中甲基对硫磷对硫磷和辛硫磷农药残留的SPE-分析测试学报.PDF

21 5 Vol. 21 No. 5 2002 9 FENXI CESHI XUEBAO( Journal of Instrum ntal Analysis) S p. 2002 SPE- HPLC 1 2 1 1 H nr K. ROTICH , 张卓勇 , 赵进英 , 李金昶 y ( 1. , 130024; 2. , 100037) : ( SPE) - ( HPLC) , 3 ; C18 , , Shim_Pack CLC ODS ( 150 mm @ 4. 6 mm id, 5 Lm) , - ( 70 B 30) , 280 nm; , : ; ; ; : X502. 2 : A : 1004- 4957( 2002) 05- 0050- 04 , , , [ 1~ 4 ] , , , , , [ 5] , 3 , , , ( SPE) , - , SPE 1 1. 1 LC_6A ( , ) , : LC_6A SPD_6AV - C_R4A CTO_6A SCL_6B 7125 ( , RHEODYNE) SHZ_D( Ó) ( 99. 5% , Sigma) ; ( 98% , Sigma) ; ( 99% , Sigma) ; ( AR, ) ; ( GR, ) ; : 2001- 11- 20; : 2002- 06- 20 : H nry Kib t Rotich( 1970- ) , , , ; , . Sourc Id ntification for S a Oil Spill Using GC- MS 1 1 2 1 ZHAO Rui_ in , SU Dan_ in , GAO Zh _chan , LIANG Zhi_ in q g q g g q ( 1. Environm ntal Monitoring Station, Guangzhou Harbour Bur au, Guangzhou 510700, China; 2. Xingang Harbour Company, Guangzhou Harbour Bur au, Guangzhou 510730, China) Abstract: A GC- MS m thod for th id ntification of s ill d oil sourc s on th s a was stablish d. Wat r sam- p l s with s ill d oil and sam l s tak n from sus ct d oil sourc s w r sub ct d to GC- MS anal s s. Thr t s p p p p j y yp of information from both typ s of sampl s w r compar dfor th id ntification of s a oil_spill sourc s, i. . , patt rns of TIC chromatograms( total ion curr nt chromatograms) , fing rprints of t r