丁香油酚的包结分离研究.PDF

·582· 　Chi ese Traditio al a d Herbal Drugs　 34 7 2003 7 * 朱德裕,吕　扬 ,郑启泰 ( ,　 100050) 　: 　-,。 　 X -。 　 1∶2 。 　-。 : ; /; X : R284. 1　　　: A　　　: 0253 2670(2003) 07 0582 03 Isolation of eugenol from volatile oil of cloves by inclusion method ·· ZHU De-yu, LU Ya g, ZHENG Qi-tai ( , , 100050, ) I stitute of Materia M edica CAM S PUMC Beiji g Chi a Abstract: Object　 To develop a ew method for isolatio of euge ol from volatile oil of cloves based . 　 o the pri ciple of molecule recog itio betw ee host a d guest Methods The crystal structures of the i clusio compou ds w ere determi ed by si gle crystal X-ray diffractio structure a alysis. Results　 The i clusio compou ds of 1, 4-be ze ediami e ( host) a d euge ol ( guest) i host ∶guest molecular ratio of 1∶2 were obtai ed. Conclusion　 The isolatio of o e chemical compo e t from mixture ca be accom- plished w ith i clusio method. Key words: i clusio compou ds; host /guest molecule; X-ray diffractio 　　 ,, [ 1, 2] 。 45 。 mL Eugenia caryophyllata Thu b. , 1. 3　: , ,。 , [3] 。、 。 [4 ] [5] , , ,, , 。 5. 0 mg 1∶2, 0. 2 mL, 20 ℃, 0. 1 mL, 。