固体酸催化合成生物柴油的分析-无机化学专业论文.docxVIP

VI VI the catalyst was studied. The result of the experiment indicated: First the solid mixture with 22.5% of SnO2 was dipped in the 1.0mol/L sulphoacid which dissolved 3% La2O3 at the proportion of 25mL/g for a period of time at a certein temperature, and then the obtained filtrate was calcinated for three hours at 550℃, the activity of the solid superacid catalyst obtained in this way is the highest. Among those complex solid superacid catalysts, whose carriers were ZrO2 or TiO2 which were made in the best condition, the activity of the catalyst of SO42-/SnO2-TiO2-ZrO2- La2O3(A) was the best, the esterification ratio of the free fat acid was 89.5%, it was better than what we have known. 3．The acid strength of the solid superacid was measured by the method of Hammett indicator, the type of activity center was analyzed by means of IR spectrum, the state of the existence and the type of the compound in the solid superacid made in different conditions were determined by the method of XRD patterns, the conclusion was: The percent of oxid mixture, the calcination temperature, the concentration and dosage of sulphoacid solution, the former state of calcination, and the species and dosage of Lanthanon could affect the acid strength, the amount and distribution of acid center, specific surface area, the sort and existing state of compound in the solid acid. 4．On the basis of analyzing that the four elements of the dynamics, the reaction temperature, the reaction time, the molor ratio of methanol-to-oil and the dosage of catalyst, impacted on the ratio of the esterification, the notable sequence and the best reaction condition that the four elements of dynamics which impacted on the ratio of esterification were obtained by the method of orthogonal experiments. Then the situation of the reuse of solid superacid made by myself was tested. The result of the emperiment indicated: These four elements of dynamics had visible effect on the ratio of esterification, the visible seq