含偶氮功能基元的聚二乙炔材料的合成及光学性质研究-高分子化学与物理专业论文.docxVIP

ABSTRACTABSTRACT ABSTRACT ABSTRACT The diacetylene(DA)derivatives have been intensely investigated due to their topochemical polymerization，the ability to form well—defined nano／microstructures as well as their subsequent elegant properties and promising applications in nonlinear optical materials，．photoresists,thermal，mechanical，chemical,and biosensors．The adjustable molecular structure of diacety’lenic monomers allows molecular architecture controlling of the supramolecular assembly，resulting in modification of morphology，stacking structure，and physical-chemical properties of polydiacetylene (PDA)． Three accessible azobenzene mesogen-substituted diacetylene monomers(DAl， DA2，and DA3)were synthesized and the effect of the molecular structure On the photopolymerization behavior and self-assembled structures of the resulting azobenzene-substituted polydiacetylene(PDA)films had been investigated in detail． The films derived from DAl were substantially polymerized into blue phase． However，the films derived from DA2 and DA3 were polymerized into red phase directly．The morphology，packing structure，and thermal stability of the resulting azobenzen．substituted PDA films were characterized in detail by SEM，XRD aS well aS POM measurements．PDA l formed micrometer-sized lamellar crystal structures， while PDA2 and PDA3 both formed spherulitic crystal structures．The strong氕—兀 stacking interaction among side chains Was essential for maintaining high stability upon thermal stimulus．This work may provide a new approach for designing and fabricating molecular assemblies with controlled size and shape，leading to the development of novel functional polymer microstmcture materials． Langmuir—Blodgett(LB)films of three azobenzene—substituted diacetylene monomers(Oa l，DA2 and DA3)were fabricated and their optical and chiroptical properties were investigated in detail by ultraviolet-visible(UV—vis)spectra and circular dichroism(CD)spectra．Achiral DA 1 molecules could form chiral LB films th