过渡金属硫化物材料的溶剂热合成与性能研究-无机化学专业论文.docxVIP

中豳科学技术大学硕士学位论文AbstractABSTRACT 中豳科学技术大学硕士学位论文Abstract ABSTRACT Recent years，mixed solvothermal process as a developing preparation method has shown its unique fascination in liquid synthesis of nanoparticles and controllable synthesis of low dimensional materials．In this thesis，all ethylenediamine—glycol mixed solution system which has good abilities of coordination，dissolution and reductivity has been used to synthesize near monodispersed NiS2 microspheres．The results can be summarized as follows： Reaction temperature，sulfur Souse and volume i-atio of the mixed solvent were crucial to synthesize the NiS2 microspheres。The results show that using NiCl2’6H20 and sulfur power as the reactants，pure NiS2 phase call not be obtained in pure ethylenediamine and also NiS2 microspheres can not be synthesized in pure glycol however,homogenous NiS2 microspheres with a diameter of about 5 micrometers have been synthesized in ethylenediamine-glycol mixed solution under mild condition。 X—ray power diffraction(XRO)patterns and scanning electron microscopy(SEM) images show that the surface structure of the microspheres can be modified by the change of the volume ratio of ethylenediamine to glycol。Transmission electron microscope(TEM)and electron diffraction results of the NiS2 slice indicates that the NiS2 microspheres possessing of a polycrystal structure which were composed of NiS2 crystallites．XRD，SEM and thermogravimetric analysis(TOA)were used to study the formation procedure and reaction meehanism of the products。Thermal stability study shows that the NiS2 can be transferred into high-crystallization meso-porous NiO microspheres in air atmosphere at high temperature，this provided us a new way of synthesizing NiO materials which has important application in catalysis，cell electrode and electrochromic fields。At last，Raman spectroscopy and Superconducting Quantum Interference Device(SQUID)were used to study the optical and magnetic properties of these two products，additionally，su