卡宾型后过渡金属配合物催化极性单体聚合-中国科技论文在线.PDFVIP

中国科技论文在线 卡宾型后过渡金属配合物催化极性单体聚 合# 1,2 1 1 2 1** 邱晓洁 ，金灿 ，强琚莉 ，沈应中 ，王乐勇 5 （1. 南京大学化学化工学院，南京 210093； 2. 南京航空航天大学材料科学与技术学院，南京 210000 ） 摘要：卡宾型后过渡金属配合物与基于 IVB 族的聚合催化剂相比，在催化极性单体聚合领 域取得了巨大的进展。本文分族介绍了卡宾型后过渡金属催化剂，尤其是氮杂环卡宾配位的 10 后过渡金属催化剂在开环易位聚合 （ROMP ）、非环双烯烃催化易位聚合 （ADMET ）等方 面的极性单体聚合的进展。本文亦指出了该类催化剂在催化反应中尚存在的不足,并对未来 的研究方向做出了展望。 关键词：有机催化；后过渡金属；催化剂；氮杂环卡宾；极性单体 中图分类号：O6-1; O621.14+7; O643.36 15 Catalyzed Polymerization of Polar Monomers by Late Transition Metal Carbene Complexes 1,2 1 1 2 1 QIU Xiaojie , JIN Can , JIANG Juli , SHEN Yingzhong , WANG Leyong (1. School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093; 20 2. College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210000) Abstract: It’s different from IV-polymerization catalysts, as late transition metal carbene complexes make tremendous progress in the field of polar monomers. This article describes the progress of polymerization of polar monomers with the type of late transition metal carbene 25 catalysts, especially the N-heterocyclic carbene(NHCs)-late transition metal carbene catalysts in the field of Ring-opening metathesis polymerization(ROMP) and Acyclic diene metathesis polymerization catalyst(ADMET). This article also points out the problems in catalytic reactions and makes prospect of further research directions. Key words: Organic synthesis; Late transition metal, Cat