过硫酸钾氧化法降解新烟碱类农药废水的研究-环境科学专业论文.docxVIP

ABSTRAC ABSTRAC T Persulfate(92082-)can be thermally chemically activated to produce powerfol oxidant sulfate free radical(·S04‘，Eo=2．6 V)which degrade many organic pollutants，such new neonicotinoid pesticide， imidacloprid，clothianidin，dinotefuran．Main research contents of this article follows：The first part was degradation of imidacloprid and clothianidin by heat activated persulfate oxidation process，the second was degradation of clothianidin by microwave—activated persulfate，and the third was degradation of dinotefuran by evaporation combined persulfate。The various factors the degradation of pesticides were studied in detail，including the temperature，pH，dosing quantity of S208}，the concentration of inorganic ion，microwave radiation time，distillation volume，etc．The free radical species in the reaction system were detected by free radical detection．The degradation products were detected by LC—MS and GC—MS，and the possible degradation mechanism was speculated． The degradation of 70％imidacloprid WDG by heat—activated persulfate showed that the degradation rate increased with the increasing temperatures．The removal imidacloprid with persulfate follows the first order kinetics．The half time of reaction were 173．28，101．93，60．80，31．36，20．32 min when the temperature increased from 50。Cto 90。C．Activation energy of reaction is 53．291kJ／m01．When the temperature was 80。C，and the concentration of potassium sulfate was 20mmol／L，the degradation rate of imidacloprid was slightly higher at neutral conditions than at alkaline and acidic condition．The degradation rate change is only 1．57％as the pH of the starting solution increases from 3 to 1 1．The addition of chlorine ion(C1。)inhibited the degradation of imidacloprid．The basic nitrate(N03’)had effect potassium persulfate oxidation of imidacloprid．The presence of bicarbonate(HC03’)had adverse effects imidacloprid degradation．However,inhibitory effects were observed in the of existing chlorine ions． The intermediate product of imid