含非线性共轭基团的聚丙烯酸酯的合成及其物理化学性质研究-高分子化学与物理专业论文.docxVIP

：皴太学臻±学位论文 ：皴太学臻±学位论文 摘要 摘 要 本论文合成了一类含非线投共轭基团的聚丙烯酸酯及其与甲基丙烯酸甲酯 的共聚物，利用多检测联用凝胶渗透色落(GPe)对聚合物的物理化学’缝质进行 了研究。主要工作内容如下： l。本论文赍缨了凝黢渗透色谱的发展，详缨搽谤了紫乡}．示差砹捡测联鲻凝跤渗 透色谱(GPC／RI．Uv)和示麓．粘度．直角激光光散射三检测凝胶渗透色谱 (GpC力姓．DV．RALLS)熬豢理察应瘸。 2．阐述了分子设计的理论基础，设计了四个目标单体，并选择了合邋的合成路 线。本论文合成了丸个证含裼，翻麓红努光谱_帮核磁共摄对亿台豹缩梭进行 了袭征。 3．采弼自由基聚合法，对西个秘标单体进行了聚合，详细研究了聚合条件(溢 度、溶剂、时阀、倦化剖比例)对浆合的影响，选撵最佳聚合条件；并将目 标单体与甲熬丙烯酸甲酯共槊，通过1H-NIvIR、IR和uV等万法对聚合物进 行了表征。 4．利用GPC／RI．DV。RALLS对四个目标单体的均聚物溶液的物理化学性质进行 了磷究，掇讨了聚念物款分子结梅与其溶滚戆凌毽化学性袋之间豹关系。鄹 用GPC／UV。RI对凝聚物的组成和组成分布进行了分析，提出了利用 UV-RI．DV-RALLS懑检溺器联惩GPC溺宠共聚甥熬分予登帮分子爨分毒豹 快速检测方法。／ 5。零j麓z．扫爨技术对戮个嚣标苯体静均聚物的非线注光学谴畿进行了礤究，发 现它们都有较好的非线性吸收效应。对聚合物的非线性吸收进行拟合，计算 得翻非线瞧吸收系数§昶三阶菲线性系数x渤，并探讨了分子结构和材料梭 能之间的关系。 关键词：多检测联用c婆c，聚_p酉烯酸黪，物理化学性质，非线性吸收，z一扫描 v／-／-／ V 麓 安徽大学?贞士学位论文 安徽大学?贞士学位论文 摘要 Abstract A kind of novel polyacrylates and poly(acrylate--CO·-methyl methacrylate)s with nonlinear optical coNugated group was synthesized．Their properties were studied with multi-detector GPC(gel permeation chromatograph)．The main contents of this dissertation consist ofthe following points： 1．The development of GPC was summarized，the prlnciple and application of double—detector GPC(GPC／UV-m)containing ultraviolet absorption(UV)and differential refractive index(RI)detectors，and the tri—detector GPC(GPC／RI—DV— RALLS)containing RI，differential viscometry(DV)and right-angle light scattering(PALLS)detectors were introduced． 2．According to the theory of nonlinear optics，four objective monomers were designed and their synthetic routes were selected．Their structures were characterized with infrared refractor(IR)and nuclear magnetic resonance spectroscopy(NMR)． 3．The objective monomers were polymefized by free radical polymerization method． Influence ofdifferent polymeric conditions，such as temperature，solvent，time and catalyst，were investigated in detMis．The copolymerizations of the objective monomers、vi也methyl methacrylate rMMA)were carried out．These polymers were characterized with_．T IV and NMR． 4．The properties of homopol