含H2S气田气井和地面集输用缓蚀剂的研究与评价-石油与天然工程专业论文.docxVIP

摘要普光气田H2S摩尔含量平均14．61％，属于超高含量H2S气田，而且CQ含量也很 摘要 普光气田H2S摩尔含量平均14．61％，属于超高含量H2S气田，而且CQ含量也很 高，达到了9．21％。由于H2S的剧毒性、H2S／C02的高腐蚀性，使该气田开发地面集输 系统面临十分突出的安全和腐蚀控制难题。 本文通过对普光气田在开采和集输中出现的腐蚀情况的分析，在实验室展开研究， 并结合现场获得的数据，对缓蚀剂的评价方法和在高含H2S气田气井和地面集输设备的 防腐中的应用做进一步的探索，使腐蚀问题得以更有效的控制。 在查阅文献和现场调研得出的结论基础上，概述了H2S和C02的腐蚀机理及其影 响条件，从电化学和物理化学等方面分析了缓蚀剂的工作机理。 根据资料调研，首先从国内油气田、大专院校和研究所等单位收集大量的应用效果 较好的缓蚀剂样品，针对气井和地面集输的不同环境情况，进行初步筛选评价，模拟环 境评价和性能评价，根据地面集输用缓蚀剂实验结果找到了一套效果较好的地面集输用 缓蚀剂组合即用OS．10做预膜缓蚀剂并用WS．10做连续加注的缓蚀剂，其腐蚀速度仅 为0．043mm／a，缓蚀率达到了94．6％，其抑制腐蚀的机理主要是预膜缓蚀剂提前在金属 表面形成保护膜阻碍了与腐蚀反应有关的电荷或物质的转移，和咪唑啉在较大程度上抑 制了腐蚀的阳极溶解过程；根据气井用缓蚀剂的实验结果发现GWS．1和GWS．2在高温 下都能形成较致密的膜，缓蚀效率都达到了97％以上，缓蚀效果良好，它们实现缓蚀的 主要机理是季铵阳离子可以吸附在带负电的金属表面形成致密的膜阻止了金属与腐蚀 介质的接触，而喹啉上的N也可以与金属表面原子的空轨道配位，在金属表面形成致密 的吸附膜，取得更好的缓蚀效果。 最后根据高含H2S和C02气田的实际工况，初步制定出现场加注方案和监测方案。 ’ ^ 关键词：硫化氢，缓蚀剂，地面集输，气井，现场 ● Study Study and Evaluation of the Inhibitor Used for Gas Wells and Surface Gathering of Natural Gas Field Containing H2S ⅥXiaodong(Petroleum and Natural Gas Engineering) Directed by A．P．Liu DexinEngineer Wang Shutao Abstract Moore content of H2S in Puguang gas field is about 14．6 1％in average．We can say its a gas field including hi曲content H2S．Besides，it has hi班content of C02 which reaches to 9．21％．Because of the hypertoxicity of H2S and highly corrosive of H2S／C02，the gas field’S ground—gathering system is confronting with the problems of extrusive safety and crossing contr01． According to the corrosion appearing in the course of exploiting，gathering and tmnsfering,we did some experiments in the lab bonding wim the data from the job site．we do fulther research to evaluation methodology of the inhibitor and its application in the gas well including hi曲content H2S as well as ground gathering and transportation equipment，SO we call make the problem of corrosion easily controlled． After turning over the books and field researcl[1，we elaborate the corrosion mechanism and affecting factors of H2S and C02．Then we analyze the working mechanism of inhibitor from the aspect of ele