含不对称液晶基元甲壳型聚对苯的设计与合成-高分子化学与物理专业论文.docxVIP

ABSTRACTThe ABSTRACT The 21st century is the information age，optical information processing，display and storage Call be accomplished wi廿l polarized light sour℃c．the polarized light call be achieved by two kinds of mechanisms：the passive and active way．At present the polarized light system ofthe liquid—crystal display mainly is a linearly polarized light． Circular polarized light SOl／IceS as well as linearly pomaded light sourccs have proven themselves indispensable in modern display technologies．Compared with the linearly polarized light monitor,Circular polarized light has the qui钯high bdghtness，nearly 100％utilization ratio of the photo source，and so Oil．At present，the reports of circularly polarized light illumination component are too few,the primary reason is there are few materials wiⅡl circularly polarized light．In order to get new materials with circularly polarized electroluminescence by effective and convenient way,a new method was proposed through designing the mesogen-jaeketed type liquid crystalline conjugated polymers with asymmetry mesogertie units． The asymmetry mesogenie unit Was designed with large dipole moment to favor it tropism under the electric field and have a regular orientation in one direction．This kind of orientation will forced the polymer chain to form a single screw direction． (induction of one·handed helix sease)As a result，the polymer will show chiroptical properties． IH-NMR,Ⅱ乙MS，GPC，DSC，UV-vis spectrum，FL spectrum and POM WaS used to characterize the intermediate product，polymer chemical constitution,the relaliye molecular weight,and optical propertied of the polymers．The relationship betweell the carapace density and the thermal and optical propertied of polymers Was alSO studies． 1H-NMR，IR,MS results confirm that the structures of all intermediate product are correct．POM and DSC results indicated that both the monomer and the删ymer form the liquid crystalline state when heated above their glass transition t瑚mperature． ii The The m