代森锰锌在烟草中的残留分析-烟草科技.PDF

/ Tobacco Science Technology/Tobacco Chemistry 2005 7 (216 ) 代森锰锌在烟草中的残留分析 , , , , , 　, , (中国农业科学院烟草研究所, 山东青岛崂山区科苑经四路 11 号　266101) :代森锰锌;乙撑硫脲; 相色谱法;高效液相色谱法 :建立了用 相色谱法和高效液相色谱法分别测定烟草中代森锰锌及其代谢物乙撑硫脲 (ETU)残留量的方法, 在0.1～10mg/ g 添加浓度范围内, 鲜烟叶、干烟叶中代森锰锌和ETU 的平均回收 率各为82.99%～97.99%和81.60%～86.17%, 变异系数分别为1.4%～7.01%和0.9%～4.2 %。 + :S482.2 2　:B　:1002-0861(2005)07-0024-03 Analysis of Mancozeb Residue in Tobacco CAO AI-HUA, XU GUANG-JUN, LI YI-QIANG, LIU BAO-AN, SUN HUI-QING, ZHENG XIAO, WANG XIN- WEI, and XU JIN-LI Qingzhou Tobacco Research Institute of CNTC, Qingdao 266101, Shandong, China Keywords:Mancozeb;Metabolite;Ethene thiourea;GC;HPLC Abstract :The analytical methods of residual mancozeb and its metabolite, ethene thiourea (ETU), in tobacco were established with GC and HPLC separately.The average recovery of mancozeb in fresh and dried leaves was 82.99% -97.99%, and that of ETUwas 81.60%-86.17%within the addition concentration of 0.1-10mg/ g, and the RSDs of mancozeb and ETU were 1.4%-7.01%and 0.9%-4.2 %, respectively . [5] 　　(mancozeb)1961 Rohm Hass , , ETU , [6] , , , , , , ETU 。 , , , , 1 　 LD505000mg/ g[1, 2] 。、、 1.1　材料 99.9%(HPLC, USA );95%、 [3] , , 95%、60 ～90 ℃、、、、 [4] 、、 。 (SnCl ·2H O )、、 2 2 FAO/WHO Na SO , AR, 2 4 (ETU)(MRL), ;、Frolisil();、Celite ETU MRL 。 545(, ); ;(, 81